{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:59:40Z","timestamp":1790319580195,"version":"4.1.0"},"reference-count":45,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22479051"],"award-info":[{"award-number":["22479051"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:p>\n                    Lithium\u2010ion batteries (LIBs) employing high\u2010nickel layered oxide cathodes are regarded as highly promising candidates for high energy density. However, operating Ni\u2010rich cathodes at elevated cut\u2010off voltage accelerates electrolyte decomposition and irreversible structural deterioration. To address these obstacles, we developed a bifunctional LiPF\n                    <jats:sub>6<\/jats:sub>\n                    \u2010based carbonate electrolyte which strategically incorporates trimethoxyboroxine (TMBO) and 1,3,6\u2010hexanetricarbonitrile (HTCN) additives to concurrently stabilize the cathode\u2013electrolyte interphase (CEI) and the bulk electrolyte. The designed electrolyte preferentially oxidizes to form a robust CEI enriched in LiF and B\u2500O species, effectively isolating the cathode from direct contact with the electrolyte and suppressing transition metals dissolution. In addition, the stability of electrolyte is improved by suppressing electrolyte decomposition and HF generation, thereby mitigating cathode structural degradation. Consequently, the designed electrolyte enables exceptional long\u2010term cycling stability, the Li\/\/NCM811 cell with a high mass loading of 12\u2009mg\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    retain 80.5% of its initial capacity after 200 cycles at 4.6\u2009V. Furthermore, the Ah\u2010level NCM811\/\/Si\u2013C pouch cell achieves long\u2010term cycling over 400 cycles with a capacity retention of 82.2% at 4.5\u2009V. This work provides an effective approach to electrolyte optimization for high\u2010voltage LIBs and offers important guidance for the design of multifunctional additives.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71102","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:16:16Z","timestamp":1790316976000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Synergistic Strategy via Interfacial and Electrolyte Stabilization Enables High\u2010Voltage Ni\u2010Rich Layered Oxide Cathodes"],"prefix":"10.1002","volume":"19","author":[{"given":"Jiajia","family":"Huang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology  Guangzhou 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