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LiNi\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Co\n                    <jats:sub>\n                      <jats:italic>y<\/jats:italic>\n                    <\/jats:sub>\n                    Al\n                    <jats:sub>z<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    is well suited to this target because its Mn\u2010free, Al\u2010stabilized layered framework offers high capacity and structural robustness, yet residual alkaline lithium species on the particle surface compromise electrode processing, interfacial kinetics and long\u2010term durability. Here we convert these residual lithium species on LiNi\n                    <jats:sub>0.88<\/jats:sub>\n                    Co\n                    <jats:sub>0.09<\/jats:sub>\n                    Al\n                    <jats:sub>0.03<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCA) surface into a functional lithium\u2013borate interphase through a boric\u2010acid\u2010mediated surface reaction (NCA\u2010B). Rather than simply removing surface residues, this strategy suppresses parasitic interfacial chemistry while maintaining efficient Li\u2010ion transport. In Ah\u2010level NCA\u2010B||graphite pouch cells, the modified cathode retains 76.9% capacity after 2000 cycles at 1\u2009C and sustains nearly decay\u2010free cycling for 2400 cycles under 1\u2009C charge and 10\u2009C discharge, with a voltage\u2010fade rate of 0.0375\u2009mV per cycle. These results establish residual\u2010lithium conversion as a practical interfacial design principle for high\u2010rate, long\u2010life NCA batteries.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71105","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T03:22:45Z","timestamp":1791170565000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Lithium\u2013Borate Interphase Enables High\u2010Rate and Long\u2010Lifespan Ni\u2010Rich Layered Oxide Cathodes"],"prefix":"10.1002","volume":"19","author":[{"given":"Yu","family":"You","sequence":"first","affiliation":[{"name":"National Research &amp; Development Center of Powder Metallurgy Powder Metallurgy Research Institute Central South University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shihong","family":"Zhao","sequence":"additional","affiliation":[{"name":"National Research &amp; Development Center of Powder Metallurgy Powder Metallurgy Research Institute Central South University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Liu","sequence":"additional","affiliation":[{"name":"National Research &amp; Development Center of Powder Metallurgy Powder Metallurgy Research Institute Central South University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Dongguan University of Technology  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinxin","family":"Wang","sequence":"additional","affiliation":[{"name":"Research Institute of Technology Minmetals New Energy Materials (Hunan) Co., Ltd.  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