{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T06:38:44Z","timestamp":1792478324386,"version":"4.5.0"},"reference-count":66,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T00:00:00Z","timestamp":1791590400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T00:00:00Z","timestamp":1791590400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22472055"],"award-info":[{"award-number":["22472055"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578116"],"award-info":[{"award-number":["22578116"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:p>\n                    Selective oxidation of biomass\u2010derived 5\u2010hydroxymethylfurfural (HMF) to 2,5\u2010diformylfuran (DFF) remains a challenge. Herein, we prepared magnesium intercalated into cryptomelane\u2010type OMS\u20102 to achieve ultrafine Mg\u2010OMS\u20102 nanorods via room\u2010temperature coprecipitation. The results confirm that Mg\n                    <jats:sup>2+<\/jats:sup>\n                    cations are incorporated into the MnO\n                    <jats:sub>6<\/jats:sub>\n                    octahedral lattice of OMS\u20102. The Mg\n                    <jats:sub>9%<\/jats:sub>\n                    \u2010OMS\u20102 with 9\u2009wt% Mg exhibits high catalytic activity for aerobic oxidation of HMF with 91% conversion and 99.9% DFF selectivity at 120\u2009\u00b0C within 1\u2009h. Experimental results and characterization demonstrate that the reaction follows the Mars\u2013van Krevelen redox mechanism. It involves a redox cycle by a reduction of high valence state of Mn ions combined with the participation of lattice oxygen, whereas surficial oxygen vacancies (O\n                    <jats:sub>vac<\/jats:sub>\n                    ) are continuously replenished by aerial soluble oxygen. The reaction rate equation of HMF oxidation is expressed dependent on O\n                    <jats:sub>2<\/jats:sub>\n                    pressure and HMF concentration. Moreover, the predicted activities agree well with the measured activities in wide ranges of HMF concentrations and O\n                    <jats:sub>2<\/jats:sub>\n                    pressures. Therefore, the ultrafine Mg\n                    <jats:sub>9%<\/jats:sub>\n                    \u2010OMS\u20102 nanorods, featuring efficient catalytic performance, facile regeneration, insightful mechanism, and kinetics descriptions present a significant potential toward practical applications.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71124","type":"journal-article","created":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T10:46:47Z","timestamp":1791629207000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Room\u2010Temperature Synthesis of Magnesium Incorporated Into OMS\u20102 Enables Highly Selective Oxidation of 5\u2010Hydroxymethylfurfural to 2,5\u2010Diformylfuran"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9004-8056","authenticated-orcid":false,"given":"Lifang","family":"Chen","sequence":"first","affiliation":[{"name":"Max Planck Partner Group at 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