{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T10:44:34Z","timestamp":1791801874468,"version":"4.3.4"},"reference-count":45,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100021856","name":"Ministero dell'Universit\u00e0 e della Ricerca","doi-asserted-by":"publisher","award":["DoE 2023\u20132027 (MUR, AIS.DIP.ECCELLENZA2023_27.FF project)"],"award-info":[{"award-number":["DoE 2023\u20132027 (MUR, AIS.DIP.ECCELLENZA2023_27.FF project)"]}],"id":[{"id":"10.13039\/501100021856","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:p>\n                    The valorization of biomass\u2010derived platform chemicals into functional monomers is a promising strategy for developing more sustainable polymeric materials. Herein, we report a versatile synthetic approach for the preparation of a library of lignocellulosic (LC) monomers by coupling 5\u2010(chloromethyl)furfural (CMF), once considered a waste product of furan production, with selected lignin\u2010derived monomers. The reaction was optimized using vanillin, affording a bis aldehyde monomer (Fur\u2010Van) in 93% yield after only 2 h under mild conditions using K\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    as the base. The methodology was successfully extended to a range of lignin\u2010derived substrates bearing different functional groups, providing a library of LC monomers in up to 94% isolated yield. The reactions were also successfully scaled up to 5\u2009g of CMF. Products were isolated without any chromatographic purification. Furthermore, the reduction of the carbonyl groups afforded the corresponding (di)ol monomers in 87%\u201398% yield. Thermal characterization revealed good thermal stability of the synthesized compounds, with degradation temperatures above 220\u2009\u00b0C for all the LC monomers. Overall, this work provides a straightforward and scalable route to multifunctional bio\u2010based monomers combining lignin\u2010derived aromatic structures with furanic moieties, offering promising building blocks for the development of bio\u2010based polymeric materials.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71131","type":"journal-article","created":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T09:44:26Z","timestamp":1791798266000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Library of Versatile Lignocellulose\u2010Derived Monomers From 5\u2010(Chloromethyl)furfural"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-4544-8717","authenticated-orcid":false,"given":"Davide","family":"Dalla Torre","sequence":"first","affiliation":[{"name":"Department of Environmental Sciences, Informatics and Statistics Ca\u2019 Foscari University of Venice  Venezia Mestre Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8951-1461","authenticated-orcid":false,"given":"Giacomo","family":"Trapasso","sequence":"additional","affiliation":[{"name":"Department of Environmental Sciences, Informatics and Statistics Ca\u2019 Foscari University of Venice  Venezia Mestre Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9946-4803","authenticated-orcid":false,"given":"Fabio","family":"Aric\u00f2","sequence":"additional","affiliation":[{"name":"Department of Environmental Sciences, Informatics and Statistics Ca\u2019 Foscari University of Venice  Venezia Mestre 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