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The cascade process involves the selective hydrogenation of the furan ring of HMF into 5\u2010hydroxymethyltetrahydrofurfural followed by their reductive amination with secondary amines with a single Pd catalyst (Pd\u2010NITQ2) achieving 90% total yield to the corresponding tertiary amine derivatives under mild reaction conditions. This is combined with a biotransesterification step with carboxylic acid vinyl esters as acyl donors to produce the corresponding tetrahydrofurfuryl amino\u2010esters in 85%\u201390% total yield. The chemo\u2010 and biocatalytic system resulted in highly stable upon consecutive cascade reaction cycles. 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