{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,9]],"date-time":"2026-02-09T08:48:53Z","timestamp":1770626933927,"version":"3.49.0"},"reference-count":31,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2006,11,2]],"date-time":"2006-11-02T00:00:00Z","timestamp":1162425600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Electrophoresis"],"published-print":{"date-parts":[[2006,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Six reducing monosaccharides (mannose, galactose, fucose, glucose, xylose, and arabinose) were derivatized with 1\u2010phenyl\u20103\u2010methyl\u20105\u2010pyrazolone (PMP) and chiral resolution of these racemic PMP\u2010monosaccharides was studied by ligand\u2010exchange CE using borate anion as a central ion of the chiral selector and (<jats:italic>S<\/jats:italic>)\u20103\u2010amino\u20101,2\u2010propanediol (SAP) as a chiral selector ligand. PMP\u2010mannose, PMP\u2010galactose and PMP\u2010fucose were successfully enantioseparated. Lowering the capillary temperature increased the resolution of PMP\u2010mannose system, but decreased that of PMP\u2010galactose and PMP\u2010fucose systems. Whereas the maximum resolution was obtained at pH\u20058.9 in the PMP\u2010mannose system, resolution increased gradually with pH in the PMP\u2010galactose and PMP\u2010fucose systems. Expecting the formation of the ternary borate complexes with SAP and PMP\u2010monosaccharide in the CE experiments, the optimized structures of the borate diastereomers were obtained by semiempirical molecular orbital calculations to discuss the structural difference of the diastereomers in connection with the enantioseparation behaviors.<\/jats:p>","DOI":"10.1002\/elps.200600140","type":"journal-article","created":{"date-parts":[[2006,11,2]],"date-time":"2006-11-02T05:07:51Z","timestamp":1162444071000},"page":"4730-4734","source":"Crossref","is-referenced-by-count":21,"title":["Chiral resolution of monosaccharides as 1\u2010phenyl\u20103\u2010methyl\u20105\u2010pyrazolone derivatives by ligand\u2010exchange CE using borate anion as a central ion of the chiral selector"],"prefix":"10.1002","volume":"27","author":[{"given":"Shuji","family":"Kodama","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sen\u2010ichi","family":"Aizawa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Atsushi","family":"Taga","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tomohisa","family":"Yamashita","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Atsushi","family":"Yamamoto","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2006,11,29]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","first-page":"284","DOI":"10.1016\/S0021-9673(00)95566-3","volume":"60","author":"Davankov V. A.","year":"1971","journal-title":"J. Chromatogr."},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.230.4727.813"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-022X(01)00145-2"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/1522-2683(200109)22:15<3107::AID-ELPS3107>3.0.CO;2-Z"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)00304-2"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200406173"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1520-667X(1996)8:5<323::AID-MCS2>3.0.CO;2-3"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.2116\/analsci.16.837"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b406875k"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200500327"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0096-5332(08)60049-1"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01173a028"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0096-5332(08)60205-2"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0096-5332(08)60240-4"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6215(00)82850-5"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)96693-1"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200500367"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0731-7085(02)00512-5"},{"key":"e_1_2_1_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200290010"},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1522-2683(19991001)20:15\/16<3134::AID-ELPS3134>3.0.CO;2-8"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00077a064"},{"key":"e_1_2_1_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(95)00237-H"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)00926-6"},{"key":"e_1_2_1_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2697(89)90444-2"},{"key":"e_1_2_1_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/0008-6215(91)84018-A"},{"key":"e_1_2_1_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)00516-7"},{"key":"e_1_2_1_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1570-0232(03)00373-8"},{"key":"e_1_2_1_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2003.09.028"},{"key":"e_1_2_1_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.540100209"},{"key":"e_1_2_1_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-461X(1996)58:2<133::AID-QUA2>3.0.CO;2-Z"},{"key":"e_1_2_1_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00435-1"}],"container-title":["ELECTROPHORESIS"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Felps.200600140","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/elps.200600140","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T11:30:33Z","timestamp":1760527833000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/elps.200600140"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,11,29]]},"references-count":31,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2006,12]]}},"alternative-id":["10.1002\/elps.200600140"],"URL":"https:\/\/doi.org\/10.1002\/elps.200600140","archive":["Portico"],"relation":{},"ISSN":["0173-0835","1522-2683"],"issn-type":[{"value":"0173-0835","type":"print"},{"value":"1522-2683","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,11,29]]}}}