{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T15:56:25Z","timestamp":1760889385846,"version":"build-2065373602"},"reference-count":30,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2017,5,11]],"date-time":"2017-05-11T00:00:00Z","timestamp":1494460800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100002923","name":"Consejo Nacional de Investigaciones Cient\u00edficas y T\u00e9cnicas","doi-asserted-by":"publisher","award":["PIP\u20100244"],"award-info":[{"award-number":["PIP\u20100244"]}],"id":[{"id":"10.13039\/501100002923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003074","name":"Agencia Nacional de Promoci\u00f3n Cient\u00edfica y Tecnol\u00f3gica","doi-asserted-by":"publisher","award":["ANPCYT 2014\u20133597","2015\u20132764"],"award-info":[{"award-number":["ANPCYT 2014\u20133597","2015\u20132764"]}],"id":[{"id":"10.13039\/501100003074","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003947","name":"Universidad Nacional de La Plata","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003947","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Electrophoresis"],"published-print":{"date-parts":[[2017,8]]},"abstract":"<jats:p>We used a permethyl\u2010<jats:italic>\u03b2<\/jats:italic>\u2010cyclodextrin chiral stationary phase under reversed\u2010phase conditions for the chiral separation of four aryloxyphenoxy\u2010propionate herbicides (fenoxaprop\u2010<jats:italic>p<\/jats:italic>\u2010ethyl, quizalofop\u2010<jats:italic>p<\/jats:italic>\u2010ethyl and tefuryl, and haloxyfop\u2010<jats:italic>p<\/jats:italic>\u2010methyl) with mixtures of methanol, ethanol, 2\u2010propanol, <jats:italic>n\u2010<\/jats:italic>propanol, <jats:italic>tert<\/jats:italic>\u2010butanol, or acetonitrile and water as mobile phases and investigated the influence of mobile phase composition and column temperature (from 0 to 50\u00b0C) on the separation. The retention factors (<jats:italic>k<\/jats:italic>) and selectivity factors (<jats:italic>\u03b1<\/jats:italic>) of all the herbicides investigated decreased with increasing temperature. The ln<jats:italic>\u03b1<\/jats:italic> versus 1\/T and ln<jats:italic>k<\/jats:italic> versus 1\/T plots for the enantiomers of the chiral pesticides were linear within the range of 0\u201350\u00b0C with all alcohol\/water mixtures constituting the mobile phase, but the ln<jats:italic>k<\/jats:italic> versus 1\/T plots were nonlinear for all the enantiomers chromatographed in acetonitrile\/water mixtures. The thermodynamic parameters based on linear van't Hoff plots were calculated. The influence of temperature and mobile phase composition on the enantioseparation of the solutes has rarely been considered simultaneously. The temperature and the solvents used in the mobile phase, however, were found to have a profound effect on the enantioseparation of these herbicides.<\/jats:p>","DOI":"10.1002\/elps.201600528","type":"journal-article","created":{"date-parts":[[2017,4,22]],"date-time":"2017-04-22T05:52:43Z","timestamp":1492840363000},"page":"1948-1955","source":"Crossref","is-referenced-by-count":9,"title":["Chiral separation of aryloxyphenoxy\u2010propionate herbicides in a permethyl\u2010\u03b2\u2010cyclodextrin based column. Influence of temperature and mobile phase composition on enantioselectivity"],"prefix":"10.1002","volume":"38","author":[{"given":"Ester","family":"Lubomirsky","sequence":"first","affiliation":[{"name":"Laboratorio de Investigaci\u00f3n y Desarrollo de M\u00e9todos Anal\u00edticos (LIDMA) and Divisi\u00f3n Qu\u00edmica Anal\u00edtica, Facultad de Ciencias Exactas UNLP  La Plata Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan M.","family":"Padr\u00f3","sequence":"additional","affiliation":[{"name":"Laboratorio de Investigaci\u00f3n y Desarrollo de M\u00e9todos Anal\u00edticos (LIDMA) and Divisi\u00f3n Qu\u00edmica Anal\u00edtica, Facultad de Ciencias Exactas UNLP  La Plata Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"H\u00e9ctor","family":"Di Loreto","sequence":"additional","affiliation":[{"name":"Agrofina S. A Laboratorio de Desarrollo Anal\u00edtico  Ciudad Aut\u00f3noma de Buenos Aires Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7498-0273","authenticated-orcid":false,"given":"Cecilia B.","family":"Castells","sequence":"additional","affiliation":[{"name":"Laboratorio de Investigaci\u00f3n y Desarrollo de M\u00e9todos Anal\u00edticos (LIDMA) and Divisi\u00f3n Qu\u00edmica Anal\u00edtica, Facultad de Ciencias Exactas UNLP  La Plata Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,5,11]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/9781444327793"},{"key":"e_1_2_8_3_1","unstructured":"Herbicide Resistance Action Committee (HRAC)Classification of herbicides according to site of action.2015.http:\/\/www.hracglobal.com\/."},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf505241t"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/ps.2780220104"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1017\/S0043174500080413"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2010.03.014"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1006\/pest.1995.1008"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4AY00364K"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/bk-1991-0471.ch001"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf000857f"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chir.20624"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.1150181236"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.1150180209"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2009.07.008"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chir.20486"},{"key":"e_1_2_8_17_1","first-page":"91","volume":"2","author":"Zhou Z. Q.","year":"2000","journal-title":"Chin. J. Pestic. Sci."},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00955-9"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1365\/s10337-010-1539-4"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chir.22593"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200600255"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac060622o"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja963076x"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/3527609431"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1201\/9780203911112"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/chir.530070412"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1093\/chromsci\/16.6.223"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(94)80402-8"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(91)80106-Q"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2010.07.043"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(94)80401-X"}],"container-title":["ELECTROPHORESIS"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Felps.201600528","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/elps.201600528","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T13:50:54Z","timestamp":1760536254000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/elps.201600528"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,5,11]]},"references-count":30,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2017,8]]}},"alternative-id":["10.1002\/elps.201600528"],"URL":"https:\/\/doi.org\/10.1002\/elps.201600528","archive":["Portico"],"relation":{},"ISSN":["0173-0835","1522-2683"],"issn-type":[{"type":"print","value":"0173-0835"},{"type":"electronic","value":"1522-2683"}],"subject":[],"published":{"date-parts":[[2017,5,11]]}}}