{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T23:26:19Z","timestamp":1777418779764,"version":"3.51.4"},"reference-count":37,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2018,2,19]],"date-time":"2018-02-19T00:00:00Z","timestamp":1518998400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21675163"],"award-info":[{"award-number":["21675163"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21405161"],"award-info":[{"award-number":["21405161"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Electrophoresis"],"published-print":{"date-parts":[[2018,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The chiral organic\u2010inorganic hybrid materials can exhibit a high loading, and the chiral selector nanoparticles can create efficient stationary phases for open\u2010tubular capillary electrochromatography (OT\u2010CEC). Hence, a novel protocol for the preparation of an OT column coated with nano\u2010amylose\u20102,3\u2010bis(3,5\u2010dimethylphenylcarbamate) (nano\u2010ABDMPC)\u2010silica hybrid sol through in situ layer\u2010by\u2010layer self\u2010assembly method was developed for CEC enantioseparation. By controlling the assembly cycle number of nano\u2010ABDMPC\u2010silica hybrid sol, a homogeneous, dense and stable coating was successfully prepared, which was confirmed by SEM and elemental analysis. As the main parameter influencing the chiral separating effect, the nano\u2010ABDMPC bearing 3\u2010(triethoxysilyl)propyl residues concentration was investigated. The experimental results showed that 10.0 mg\/mL nano\u2010ABDMPC bearing 3\u2010(triethoxysilyl)propyl residues coated OT capillary column possessed chiral recognition ability toward the six enantiomers (phenylalanine, tyrosine, tryptophan, phenethyl alcohol, 1\u2010phenyl\u20102\u2010propanol, and Tr\u00f6ger's base) at some of the different conditions tested. Additionally, the coated OT column revealed adequate repeatability concerning run\u2010to\u2010run, day\u2010to\u2010day and column\u2010to\u2010column. These results demonstrated the promising applicability of nano\u2010ABDMPC\u2010silica hybrid sol coated OT column in CEC enantioseparations.<\/jats:p>","DOI":"10.1002\/elps.201700358","type":"journal-article","created":{"date-parts":[[2018,1,31]],"date-time":"2018-01-31T00:02:54Z","timestamp":1517356974000},"page":"1086-1095","source":"Crossref","is-referenced-by-count":8,"title":["Nano\u2010amylose\u20102,3\u2010bis(3,5\u2010dimethylphenylcarbamate)\u2010silica hybrid sol immobilized on open tubular capillary column for capillary electrochromatography enantioseparation"],"prefix":"10.1002","volume":"39","author":[{"given":"Yaming","family":"Sun","sequence":"first","affiliation":[{"name":"CAS Key laboratory of Chemistry of Northwestern Plant Resources and Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences  Lanzhou P.\u00a0R.\u00a0China"},{"name":"University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qi","family":"Wu","sequence":"additional","affiliation":[{"name":"CAS Key laboratory of Chemistry of Northwestern Plant Resources and Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences  Lanzhou P.\u00a0R.\u00a0China"},{"name":"University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaofeng","family":"Shi","sequence":"additional","affiliation":[{"name":"Institute of Materia Medica Gansu Academy of Medical Science Key Laboratory of TCM Pharmacology and Toxicology of Gansu Province  Lanzhou P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jie","family":"Gao","sequence":"additional","affiliation":[{"name":"CAS Key laboratory of Chemistry of Northwestern Plant Resources and Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences  Lanzhou P.\u00a0R.\u00a0China"},{"name":"University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9960-9822","authenticated-orcid":false,"given":"Shuqing","family":"Dong","sequence":"additional","affiliation":[{"name":"CAS Key laboratory of Chemistry of Northwestern Plant Resources and Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences  Lanzhou P.\u00a0R.\u00a0China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liang","family":"Zhao","sequence":"additional","affiliation":[{"name":"CAS Key laboratory of Chemistry of Northwestern Plant Resources and Key laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences  Lanzhou P.\u00a0R.\u00a0China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,2,19]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2010.11.001"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2009.09.024"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2012.01.003"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201300035"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar500096q"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.6b01643"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2013.05.051"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)01004-2"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200500388"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2010.11.001"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200305403"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200700631"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2005.12.039"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200700525"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/1522-2683(200209)23:17<2973::AID-ELPS2973>3.0.CO;2-U"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2004.04.056"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201100689"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201400085"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2014.05.029"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jchromb.2008.07.017"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200900456"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.09.022"},{"key":"e_1_2_8_24_1","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1016\/S0021-9673(97)01004-2","volume":"796","author":"Francoa P.","year":"1998","journal-title":"J. Chromatogr. A"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2014.09.002"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbpol.2017.02.060"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201000410"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2011.07.091"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/star.201400182"},{"key":"e_1_2_8_30_1","doi-asserted-by":"crossref","first-page":"516","DOI":"10.3390\/molecules21040516","volume":"21","author":"Zhang X.","year":"2016","journal-title":"Molecules"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200800841"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja020828g"},{"key":"e_1_2_8_33_1","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1016\/0021-9673(96)00208-7","volume":"741","author":"Bootha T. D.","year":"1996","journal-title":"J. Chromatogr. A"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201000410"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2017.09.017"},{"key":"e_1_2_8_36_1","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1016\/j.jpba.2015.12.007","volume":"121","author":"Albalsa D.","year":"2016","journal-title":"J. Pharmaceut. Biomed."},{"key":"e_1_2_8_37_1","doi-asserted-by":"crossref","first-page":"2807","DOI":"10.1002\/elps.201400169","volume":"35","author":"Albalsa D.","year":"2014","journal-title":"Electrophoresis"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.200800025"}],"container-title":["ELECTROPHORESIS"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Felps.201700358","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/elps.201700358","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T08:08:26Z","timestamp":1760515706000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/elps.201700358"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,2,19]]},"references-count":37,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2018,4]]}},"alternative-id":["10.1002\/elps.201700358"],"URL":"https:\/\/doi.org\/10.1002\/elps.201700358","archive":["Portico"],"relation":{},"ISSN":["0173-0835","1522-2683"],"issn-type":[{"value":"0173-0835","type":"print"},{"value":"1522-2683","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,2,19]]}}}