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Here, we report a novel assay for studying the self\u2010assembly of QDs and peptide, based on CE using a bending capillary. We demonstrate that the semicircles numbers of the bending capillary affect the self\u2010assembly kinetics of CdSe\/ZnS QDs and ATTO\u2010D<jats:sub>3<\/jats:sub>LVPRGSGP<jats:sub>9<\/jats:sub>G<jats:sub>2<\/jats:sub>H<jats:sub>6<\/jats:sub> peptide. Moreover, benefitting from this novel assay, the effect of the position on the self\u2010assembly has also been realized. More importantly, we also demonstrate that this novel assay can be used for studying the stability of the QDs\u2013peptide complex inflow. We believe that our novel assay proposed in this work could be further used as a general strategy for the studying nanoparticle\u2013biomolecule interaction or biomolecule\u2013biomolecule interaction.<\/jats:p>","DOI":"10.1002\/elps.201800466","type":"journal-article","created":{"date-parts":[[2018,12,13]],"date-time":"2018-12-13T03:52:56Z","timestamp":1544673176000},"page":"1019-1026","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Resolving quantum dots and peptide assembly and disassembly using bending capillary electrophoresis"],"prefix":"10.1002","volume":"40","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3133-6132","authenticated-orcid":false,"given":"Jianhao","family":"Wang","sequence":"first","affiliation":[{"name":"School of Pharmaceutical Engineering and Life Science Changzhou University  Changzhou P. R. 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