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Biomass containing plentiful and renewable carbon resources is regarded to be a desired alternative for fossil fuel. Recently, research community has paid remarkable attention to develop the catalytic processes to produce fuels and chemicals from lignocellulosic biomass. This review surveys the recent advances of several representative novel catalytic materials with precise crystalline structures for key biomass platform chemicals (glucose, levulinic acid, 5\u2010hydroxymethylfurfural, and furfural) conversion processes, including oxidation, hydrogenation, and cascade reactions. The mechanistic reaction pathways are discussed, as well as the active sites and catalyst design. 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