{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T21:44:22Z","timestamp":1791236662356,"version":"4.1.0"},"reference-count":44,"publisher":"Oxford University Press (OUP)","issue":"10","license":[{"start":{"date-parts":[[2012,7,21]],"date-time":"2012-07-21T00:00:00Z","timestamp":1342828800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/academic.oup.com\/pages\/standard-publication-reuse-rights"},{"start":{"date-parts":[[2012,8,7]],"date-time":"2012-08-07T00:00:00Z","timestamp":1344297600000},"content-version":"vor","delay-in-days":17,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["setac.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2012,10,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>The mechanism of oxytetracycline (OTC) adsorption to a silty clay loam soil was investigated using sorption isotherm experiments, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction spectroscopy (XRD). Sorption data fit well to a cation-exchange capacity sorption model. Spectroscopic data indicate that the interactions between oxytetracycline and silty clay loam soil were primarily through electrostatic interactions between the protonated dimethylamino group of OTC and the negatively charged moieties on the surface of the soil. Based on XRD results, OTC adsorption appeared to inhibit the ethylene glycol solvation of the expandable clay minerals, suggesting that OTC had diffused into the clay interlayer space. The presence of adsorbed OTC did not significantly affect the transformation frequency of the soil bacterium Azotobacter vinelandii with plasmid DNA (soil alone 3\u2009\u00d7\u2009106\u2009\u00b1\u20094\u2009\u00d7\u2009106 and soil with adsorbed OTC 4\u2009\u00d7\u2009106\u2009\u00b1\u20090.5\u2009\u00d7\u2009106). Growth was inhibited by adsorbed OTC, although a greater mass of adsorbed OTC was required to achieve the same degree of inhibition as the system of dissolved OTC alone. These results suggest that the interactions of tetracyclines at the soil\u2013water interface will affect the growth of sensitive microorganisms in soil microbial communities. Environ. Toxicol. Chem. 2012; 31: 2217\u20132224. \u00a9 2012 SETAC<\/jats:p>","DOI":"10.1002\/etc.1945","type":"journal-article","created":{"date-parts":[[2012,7,22]],"date-time":"2012-07-22T04:04:38Z","timestamp":1342929878000},"page":"2217-2224","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Oxytetracycline interactions at the soil\u2013water interface: Effects of environmental surfaces on natural transformation and growth inhibition of <i>Azotobacter vinelandii<\/i>"],"prefix":"10.1093","volume":"31","author":[{"given":"Heather E.","family":"Goetsch","sequence":"first","affiliation":[{"name":"Department of Civil and Environmental Engineering, University of Illinois at Urbana\u2013Champaign, Urbana, Illinois, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Steven E.","family":"Mylon","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Lafayette College, Easton, Pennsylvania, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shane","family":"Butler","sequence":"additional","affiliation":[{"name":"Illinois State Geological Survey, University of Illinois at Urbana\u2013Champaign, Urbana, Illinois, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julie L.","family":"Zilles","sequence":"additional","affiliation":[{"name":"Department of Civil and Environmental Engineering, University of Illinois at Urbana\u2013Champaign, Urbana, Illinois, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thanh H.","family":"Nguyen","sequence":"additional","affiliation":[{"name":"Department of Civil and Environmental Engineering, University of Illinois at Urbana\u2013Champaign, Urbana, Illinois, 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