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At present, its manufacturing production is still dominated by century\u2010old Haber\u2013Bosch process, involving in huge amounts of energy consumptions and carbon dioxide emissions. Hence, it is of great significance to develop green and sustainable alternative technologies, such as photo\u2010, thermo\u2010, and electro\u2010catalytic syntheses of ammonia. Nevertheless, the intrinsic inertness of nitrogen results in low ammonia yield of above candidates, which still cannot meet commercialization expectations. Recent researches have successfully demonstrated that plasma can effectively activate the decomposition of nitrogen and hydrogen under ambient conditions, thereby significantly improving the ammonia yield of these alternative strategies. This review systematically summarizes the classification and reaction mechanism of plasma for this reason, and discusses the synergy between different plasma and catalytic methods along with energy consumptions in detail. In the meantime, the future development trend is also forecasted.<\/jats:p>","DOI":"10.1002\/exp.20240438","type":"journal-article","created":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T09:51:11Z","timestamp":1770285071000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Plasma Activate Nitrogen for Efficient Ammonia Synthesis"],"prefix":"10.1002","volume":"6","author":[{"given":"Yamei","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemical and Pharmaceutical Engineering Hebei University of Science and Technology  Shijiazhuang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianfei","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemical and Pharmaceutical Engineering Hebei University of Science and Technology  Shijiazhuang 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