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In this work, carbon dots (CDs) synthesized from gallic acid and polyethylenimine are used for the efficient catalytic cycloaddition of CO\n                    <jats:sub>2<\/jats:sub>\n                    with epoxides in the absence of any solvent, additives, and halides, and importantly upon irradiation by natural sunlight. Specifically, carbon dots generated thermal energy and electrons upon solar irradiation, which together with their surface N\u2010sites activated the inert CO\n                    <jats:sub>2<\/jats:sub>\n                    . Meanwhile, epoxides were activated by the surface hydroxyl and carboxylic groups of the carbon dots, which reacted with activated CO\n                    <jats:sub>2<\/jats:sub>\n                    at solar thermal\u2010induced high temperatures. The CDs shows excellent stability and recyclability during the catalysis. A 1000\u00a0mmol scale reaction for cyclic carbonate synthesis performed well upon irradiation with natural sunlight in the presence of CDs, showing great potential for the industrial application due to the simple, mild, and energy\u2010saving process.\n                  <\/jats:p>","DOI":"10.1002\/exp.20250043","type":"journal-article","created":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T07:39:43Z","timestamp":1770881983000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Sunlight\u2010Driven Fixation of CO\n                    <sub>2<\/sub>\n                    to Cyclic Carbonates Using Carbon Dots as a Photothermal Catalyst"],"prefix":"10.1002","volume":"6","author":[{"given":"Ruijia","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Woody Oil Resources Utilization Northeast Forestry University  Harbin 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Bio\u2010based Material Science and Technology of Ministry of Education Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bernd","family":"Strehmel","sequence":"additional","affiliation":[{"name":"Department of Chemistry Institute for Coatings and Surface Chemistry Niederrhein University of Applied Sciences  Krefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shouxin","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Woody Oil Resources Utilization Northeast Forestry University  Harbin China"},{"name":"Key Laboratory of Bio\u2010based Material Science and Technology of Ministry of Education Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey L.","family":"Rogach","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Centre for Functional Photonics (CFP) City 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