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This study unveils a pioneering solution via a novel cold\u2010adapted ligninolytic nanozyme constructed from an amorphous manganese\u2010containing metal\u2010organic framework (aMnMOF). The aMnMOF features low\u2010coordination Mn within mixed\u2010valence trinuclear Mn\u2010O clusters integrated with a long\u2010range disordered MOF architecture. This unique design significantly lowered the reaction energy barrier of the rate\u2010determining step to an exothermic process, endowing it with broad\u2010spectrum oxidase\u2010like activities over a wide temperature range (4\u00b0C\u201337\u00b0C) without additional oxidants. Based on these advancements, aMnMOF serves not only as a superior nanozyme for oxidative degradation of monomeric, dimeric and complex lignin compounds, but also as a sustainable pathway for real kraft black liquor treatment even under cold conditions, underscoring its superiority over existing methods. This innovative discovery not only advances the rational design of cold\u2010adapted nanozymes but also provides a significant breakthrough in the field of industrial wastewater treatment.<\/jats:p>","DOI":"10.1002\/exp2.70237","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T04:02:17Z","timestamp":1791432137000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cold\u2010adapted Ligninolytic Nanozyme Unveiling New Horizons in Black Liquor Treatment Under Mild Condition"],"prefix":"10.1002","volume":"6","author":[{"given":"Qing","family":"Tian","sequence":"first","affiliation":[{"name":"School of Life Sciences and Technology Northwestern Polytechnical University  Xi'an China"},{"name":"Nanozyme Laboratory in Zhongyuan Henan Academy of Innovations in Medical Science  Zhengzhou 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