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This allowed us to observe if these compounds contributed to corrosion and the migration of iron and tin compounds from the cans to the tomatoes. Diced Roma tomatoes and other simulant treatment groups were sealed in two\u2010piece tinplated cans (controls in glass jars), retorted at 121\u2103 for 30\u00a0min, then stored at 49\u2103 for 50\u00a0days. Results showed that thermal degradation of amino acids in the tomatoes gave rise to volatile methyl sulfides and nonvolatile nitrogenous compounds which were subsequently sorbed by the can lining. SIFT\u2010MS showed a 20\u2010fold increase in dimethyl sulfide concentration. Inductively coupled plasma (ICP\u2010MS) results showed fourfold and 16\u2010fold increases in iron and tin compounds, respectively, that migrated from the metal to the tomatoes as a result of acid and electrolyte interactions.<\/jats:p>","DOI":"10.1002\/fsn3.2376","type":"journal-article","created":{"date-parts":[[2021,6,27]],"date-time":"2021-06-27T13:13:35Z","timestamp":1624799615000},"page":"4134-4145","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Heat\u2010induced compounds development in processed tomato and their influence on corrosion initiation in metal food cans"],"prefix":"10.1002","volume":"9","author":[{"given":"Elliot","family":"Dhuey","sequence":"first","affiliation":[{"name":"Department of Food Science and Technology The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hardy Z.","family":"Castada","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheryl","family":"Barringer","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jojo","family":"Joseph","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christopher M.","family":"Hadad","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ken","family":"Ruffley","sequence":"additional","affiliation":[{"name":"Kenneth J Ruffley LLC Cincinnati OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3601-4012","authenticated-orcid":false,"given":"Melvin A.","family":"Pascall","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology The Ohio State University Columbus OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,6,27]]},"reference":[{"key":"e_1_2_11_2_1","volume-title":"Tomatoes | Agricultural marketing resource center","author":"AgMRC","year":"2018"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/jsfa.2740590115"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.7089"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/sca.4950190710"},{"key":"e_1_2_11_6_1","volume-title":"Polymer permeability","author":"Comyn J.","year":"2012"},{"key":"e_1_2_11_7_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-2621.1970.tb02002.x"},{"key":"e_1_2_11_8_1","doi-asserted-by":"publisher","DOI":"10.1533\/9781845696146"},{"issue":"3","key":"e_1_2_11_9_1","article-title":"the use of the scanning electron microscope in investigating container corrosion by canned foods and beverages","volume":"9","author":"Helwig E.","year":"1990","journal-title":"Food Structure"},{"key":"e_1_2_11_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2005.06.004"},{"key":"e_1_2_11_11_1","doi-asserted-by":"publisher","DOI":"10.1201\/9780203734285"},{"key":"e_1_2_11_12_1","doi-asserted-by":"publisher","DOI":"10.1080\/10408398209527354"},{"key":"e_1_2_11_13_1","doi-asserted-by":"publisher","DOI":"10.1104\/pp.93.2.623"},{"key":"e_1_2_11_14_1","first-page":"7","article-title":"Effect of elemental sulfur on pitting corrosion of steels","volume":"18","author":"Nagu M.","year":"2018","journal-title":"Insights in Analytical Electrochemistry"},{"key":"e_1_2_11_15_1","doi-asserted-by":"publisher","DOI":"10.1080\/02652030903161580"},{"key":"e_1_2_11_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac1009723"},{"key":"e_1_2_11_17_1","doi-asserted-by":"publisher","DOI":"10.1179\/147842204X2808"},{"key":"e_1_2_11_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-002-1420-x"},{"key":"e_1_2_11_19_1","doi-asserted-by":"publisher","DOI":"10.1080\/87559128609540802"},{"issue":"9","key":"e_1_2_11_20_1","first-page":"1163","article-title":"Nitrates, agriculture and environment","volume":"79","author":"Rao E. 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