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Here, the first demonstration of a zinc compound\/silicone hybrid foam is reported for amperometric sensing of glucose oxidase. The silicone foam is fabricated by a self\u2010developed solid\u2010filling\u2010melting method. Two zinc\u2010based polymers, Zn\u2010Compound\u20101 and Zn\u2010Compound\u20102, are synthesized. Zn\u2010Compound\u20101 and Zn\u2010Compound\u20102 are characterized by X\u2010ray diffraction, X\u2010ray photoelectron spectroscopy, Fourier\u2010transform infrared spectroscopy, Raman spectroscopy, and X\u2010ray absorption nearedge structure spectroscopy of carbon K\u2010edge, oxygen K\u2010edge, and zinc L\u2010edge. Effective amperometric sensing of glucose oxidase is achieved by introducing Zn\u2010Compound\u20101 or Zn\u2010Compound\u20102 into the silicone foam, i.e., an increase of the concentration of the glucose oxidase led to an increase of detected current. This phenomenon can be explained by a possible mechanism of the formation of electron extra bands.<\/jats:p>","DOI":"10.1002\/gch2.201800049","type":"journal-article","created":{"date-parts":[[2018,11,26]],"date-time":"2018-11-26T07:05:09Z","timestamp":1543215909000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["3D Macroporous Zinc Compound\/Silicone Hybrid Foams for Amperometric Sensing of Glucose Oxidase"],"prefix":"10.1002","volume":"3","author":[{"given":"Ye","family":"Wu","sequence":"first","affiliation":[{"name":"Division of Electrical and Computer Engineering Louisiana State University  Baton Rouge LA 70803 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Fu","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Mcgill University  817 Sherbrooke St. West Montreal Quebec H3A 0C3 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiwei","family":"Xie","sequence":"additional","affiliation":[{"name":"Department of Chemistry Louisiana State University  Baton Rouge LA 70803 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7478-3103","authenticated-orcid":false,"given":"Yingcheng","family":"Lin","sequence":"additional","affiliation":[{"name":"Key Laboratory of Dependable Service Computing in Cyber Physical Society (Chongqing University) of Ministry of Education  Chongqing 400044 China"},{"name":"College of Communication Engineering Chongqing University  Chongqing 400044 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Orhan","family":"Kizilkaya","sequence":"additional","affiliation":[{"name":"Center for Advanced Microstructures and Devices Louisiana State University  6980 Jefferson Hwy. 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