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Here, the adsorption of difluoromethane (R\u201032), pentafluoroethane (R\u2010125), and 1,1,1,2\u2010tetrafluoroethane (R\u2010134a) is studied in four metal\u2013organic frameworks (MOFs: Cu\u2010benzene\u20101,3,5\u2010tricarboxylate, zeolitic imidazolate framework\u20108, MOF\u2010177, and MIL\u201053(Al)) and in one zeolite (ZSM\u20105) with the aim to develop technologies for the efficient capture and separation of high global warming potential blends containing these gases. Single\u2010component sorption equilibria of the pure gases are measured at three temperatures (283.15, 303.15, and 323.15\u00a0K) by gravimetry and correlated using the T\u00f3th and Virial adsorption models, and selectivities toward R\u2010410A and R\u2010407F are determined by ideal adsorption solution theory. While at lower pressures, R\u2010125 and R\u2010134a are preferentially adsorbed in all materials, at higher pressures there is no selectivity, or it is shifted toward the adsorption R\u201032. Furthermore, at high pressures, MOF\u2010177 shows the highest adsorption capacity for the three F\u2010gases. The results presented here show that the utilization of MOFs, as tailored made materials, is promising for the development of new approaches for the selective capture of F\u2010gases and for the separation of blends of these gases, which are used in commercial refrigeration.<\/jats:p>","DOI":"10.1002\/gch2.202200107","type":"journal-article","created":{"date-parts":[[2022,10,21]],"date-time":"2022-10-21T19:05:04Z","timestamp":1666379104000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Exploring the Potential of Metal\u2013Organic Frameworks for the Separation of Blends of Fluorinated Gases with High Global Warming Potential"],"prefix":"10.1002","volume":"7","author":[{"given":"Julio E.","family":"Sosa","sequence":"first","affiliation":[{"name":"Department of Chemistry LAQV REQUIMTE NOVA School of Science and Technology NOVA University Lisbon  Caparica 2829\u2010516 Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carine","family":"Malheiro","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Pau et des Pays de l'Adour E2S UPPA CNRS TOTAL LFCR  Anglet 64600 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paulo J.","family":"Castro","sequence":"additional","affiliation":[{"name":"Department of Chemistry LAQV REQUIMTE NOVA School of Science and Technology NOVA University Lisbon  Caparica 2829\u2010516 Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui P. P. L.","family":"Ribeiro","sequence":"additional","affiliation":[{"name":"Department of Chemistry LAQV REQUIMTE NOVA School of Science and Technology NOVA University Lisbon  Caparica 2829\u2010516 Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuel M.","family":"Pi\u00f1eiro","sequence":"additional","affiliation":[{"name":"Departamento de F\u00edsica Aplicada Facultade de Ciencias Universidade de Vigo  Vigo E36310 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fr\u00e9d\u00e9ric","family":"Plantier","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Pau et des Pays de l'Adour E2S UPPA CNRS TOTAL LFCR  Anglet 64600 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jos\u00e9 P. 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