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The chemical industry is responsible for almost 2% of all CO\n                    <jats:sub>2<\/jats:sub>\n                    emissions, with half of it coming from the production of simple commodity chemicals, such as NH\n                    <jats:sub>3<\/jats:sub>\n                    , H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , methanol, and aniline. Despite electrolysis driven by renewable power sources emerging as the most promising way to supply all the green hydrogen required in the production chain of these chemicals, in this review, it is worth noting that the photocatalytic route may be underestimated and can hold a bright future for this topic. In fact, the production of H\n                    <jats:sub>2<\/jats:sub>\n                    by photocatalysis still faces important challenges in terms of activity, engineering, and economic feasibility. However, photocatalytic systems can be tailored to directly convert sunlight and water (or other renewable proton sources) directly into chemicals, enabling a solar\u2010to\u2010chemical strategy. Here, a series of recent examples are presented, demonstrating that photocatalysis can be successfully employed to produce the most important commodity chemicals, especially on NH\n                    <jats:sub>3<\/jats:sub>\n                    , H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , and chemicals produced by reduction reactions. The replacement of fossil\u2010derived H\n                    <jats:sub>2<\/jats:sub>\n                    in the synthesis of these chemicals can be disruptive, essentially safeguarding the transition of the chemical industry to a low\u2010carbon economy.\n                  <\/jats:p>","DOI":"10.1002\/gch2.202300185","type":"journal-article","created":{"date-parts":[[2023,11,21]],"date-time":"2023-11-21T17:06:13Z","timestamp":1700586373000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["A Solar to Chemical Strategy: Green Hydrogen as a Means, Not an End"],"prefix":"10.1002","volume":"8","author":[{"given":"Gabriel A. A.","family":"Diab","sequence":"first","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. Washington Lu\u00eds km 235 \u2013 SP S\u00e3o Carlos SP 13565\u2010905 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcos A. R.","family":"da Silva","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. Washington Lu\u00eds km 235 \u2013 SP S\u00e3o Carlos SP 13565\u2010905 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guilherme F. S. R.","family":"Rocha","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. Washington Lu\u00eds km 235 \u2013 SP S\u00e3o Carlos SP 13565\u2010905 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luis F. G.","family":"Noleto","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. Washington Lu\u00eds km 235 \u2013 SP S\u00e3o Carlos SP 13565\u2010905 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Rogolino","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  Cambridge CB3 0HE UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jo\u00e3o P.","family":"de Mesquita","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. Washington Lu\u00eds km 235 \u2013 SP S\u00e3o Carlos SP 13565\u2010905 Brazil"},{"name":"Departamento de Qu\u00edmica Universidade Federal dos Vales Jequitinhonha e Mucuri  Rodovia MGT 367 \u2013 Km 583, n\u00b0 5000, Alto da Jacuba Diamantina MG 39100 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pablo","family":"Jim\u00e9nez\u2010Calvo","sequence":"additional","affiliation":[{"name":"Department for Materials Sciences Friedrich\u2010Alexander\u2010Universit\u00e4t Erlangen\u2010N\u00fcrnberg  Martensstrasse 7 D\u201091058 Erlangen Germany"},{"name":"Chemistry of Thin Film Materials Friedrich\u2010Alexander\u2010Universit\u00e4t Erlangen\u2010N\u00fcrnberg  IZNF, Cauerstra\u00dfe 3 D\u201091058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4356-061X","authenticated-orcid":false,"given":"Ivo F.","family":"Teixeira","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of S\u00e3o Carlos  Rod. 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