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Subsurface mineral carbonation is the safest method of CCS, where water\u2010dissolved CO\n                    <jats:sub>2<\/jats:sub>\n                    is injected into the subsurface and reacts with mafic or ultramafic minerals that release cations (Ca\n                    <jats:sup>2+<\/jats:sup>\n                    , Mg\n                    <jats:sup>2+<\/jats:sup>\n                    , Fe\n                    <jats:sup>2+<\/jats:sup>\n                    ), resulting in the formation of carbonate minerals. However, more research is needed to effectively implement CCS in basaltic reservoirs. In these experiments, it is shown how two different samples (basaltic glass and basaltic crystals) react to carbonation under identical conditions: a pH of around 6.5, reaction times of 2 and 5 days, temperatures of 100\u00b0C and 200\u00b0C, and absolute pressures from 70 to 85 bar(a) at the operating temperatures. The results show partial dissolution of mineral phases, formation of new alteration phases, and carbonate precipitation. This study aims to identify key variables to analyze in such experiments to evaluate the formation of CO and CH\n                    <jats:sub>4<\/jats:sub>\n                    as an alternative reaction pathway during mineral carbonation of injected CO\n                    <jats:sub>2<\/jats:sub>\n                    in basalts. Ultimately, this research aims to lay the groundwork for future studies on basalt carbonation and on how the CCS process might be influenced by CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to CO and CH\n                    <jats:sub>4<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/gch2.70147","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T03:52:34Z","timestamp":1786593154000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Concomitant Mineral Carbonation and CO\n                    <sub>2<\/sub>\n                    Reduction in Short\u2010Term Water\u2010Basalts Reaction: Difference Between Basaltic Glass and Basaltic Crystals"],"prefix":"10.1002","volume":"10","author":[{"given":"Andrea","family":"Pierozzi","sequence":"first","affiliation":[{"name":"iCRAG Department of Geology School of Natural Sciences Trinity College Dublin  Dublin Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R\u00e9mi","family":"Rateau","sequence":"additional","affiliation":[{"name":"Department of Geology School of Natural Sciences Trinity College Dublin  Dublin Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Orlando","sequence":"additional","affiliation":[{"name":"CNR\u2014Consiglio Nazionale delle Ricerche Istituto di Geoscienze  Florence Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniele","family":"Borrini","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze della Terra \u2013 Universit\u00e0 di Firenze  Florence Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franco","family":"Tassi","sequence":"additional","affiliation":[{"name":"CNR\u2014Consiglio Nazionale delle Ricerche Istituto di Geoscienze  Florence Italy"},{"name":"Dipartimento di Scienze della Terra \u2013 Universit\u00e0 di Firenze  Florence Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan Diego","family":"Rodriguez\u2010Blanco","sequence":"additional","affiliation":[{"name":"iCRAG Department of Geology School of Natural Sciences Trinity College Dublin  Dublin Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,12]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/aisy.202300168"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/2016GB005546"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/2014GB004997"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esr.2018.08.003"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.2138\/rmg.2013.75.4"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.lithos.2017.04.002"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1093\/petrology\/28.2.389"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/0016\u20107037(90)90431\u2010J"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.2113\/gselements.4.5.305"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1029\/2005JB004169"},{"key":"e_1_2_9_12_1","first-page":"470","volume-title":"Geological Sequestration of Carbon Dioxide. 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