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Stainless steel columns were used for the sorption experiments in nonequilibrium conditions. Obtained results were modeled using the advective-dispersive equation under nonequilibrium conditions. Transport of these compounds through the alluvial sediment column showed that the retention time increased with increasing molecular hydrophobicity. Inoculated biochar increases the retardation of both compounds: twofold for pentachlorobenzene compared with alachlor as a consequence of a higher hydrophobicity. Obtained results indicate that the highest biodegradation coefficient was observed for pentachlorobenzene (\u03bb\u2009=\u200910) in alluvial sediment with addition of an inoculated hydrochar, which is assumed to be a consequence of biosorption. Moreover, all experiments on the columns indicate that the addition of inoculated chars yields a significantly higher Rd coefficient for pentachlorobenzene than for alachlor. Bacterial counts increased in all of the column experiments, which indicates the successful adaptation of microorganisms to experimental conditions and their potential for the removal of a large number of organic pollutants. Thus, addition of inoculated chars to contaminated sediments has the potential as a remediation technique to inhibit the leaching of pollutants to groundwaters. Integr Environ Assess Manag 2023;19:933\u2013942. \u00a9 2022 SETAC<\/jats:p>","DOI":"10.1002\/ieam.4691","type":"journal-article","created":{"date-parts":[[2022,9,27]],"date-time":"2022-09-27T10:11:04Z","timestamp":1664273464000},"page":"933-942","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Microbially inoculated chars strongly reduce the mobility of alachlor and pentachlorobenzene in an alluvial sediment"],"prefix":"10.1093","volume":"19","author":[{"given":"Irina","family":"Jevrosimov","sequence":"first","affiliation":[{"name":"Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences University of Novi Sad Novi Sad R. 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