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Different coatings were produced by electrolysis for 3 and 10 h at a constant current density of 10 mA\/cm<jats:sup>2<\/jats:sup>. X\u2010ray diffraction and X\u2010ray fluorescence were used to identify the phases and chemical composition respectively. Thickness of the coatings was measured using ellipsometry. Electrochemical polarization and AC impedance studies were performed on the coatings by exposing them to simulated body fluid (SBF) for a period of 1 week. The coating produced by 10\u2010h electrolysis from bath of Ca\/P ratio 15 showed low corrosion current and high impedance to the week\u2010long attack of SBF. \u00a9 2007 Wiley Periodicals, Inc. 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