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The partitioning of the reaction path into different domains of structural stability has been done within the framework of the electron localization function (ELF) analysis. It has been found that DMA cluster size is a key parameter in modulating CO<jats:sub>2<\/jats:sub> conversion, both energetically and structurally. It has been shown that as the size of DMA clusters increases, hidden domains transform into real domains and the energy barrier for the rate\u2010limiting step significantly decreases, so that a slow and unlikely reaction becomes an instantaneous and viable reaction. Carbamic acid hydrogen bonded with a DMA dimer is the unique product of the reaction of CO<jats:sub>2<\/jats:sub> with a DMA trimer.<\/jats:p>","DOI":"10.1002\/jcc.70135","type":"journal-article","created":{"date-parts":[[2025,5,15]],"date-time":"2025-05-15T05:04:10Z","timestamp":1747285450000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Modulation of the Product Upon the Reaction of <scp>CO<sub>2<\/sub><\/scp> With Dimethylamine Cluster: A Topological Analysis of the Reaction Mechanism"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8412-4147","authenticated-orcid":false,"given":"Mohammad Esma\u00efl","family":"Alikhani","sequence":"first","affiliation":[{"name":"MONARIS, CNRS\u2010UMR 8233 Sorbonne Universit\u00e9  Paris 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