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Purifying the solvents to meet reuse specifications can be challenging. For hydrophilic solvents, water must be removed prior to reuse, yet many hydrophilic solvents form hard\u2010to\u2010separate azeotropic mixtures with water. Such mixtures make separation processes energy\u2010intensive and cause economic challenges. The membrane processes pervaporation (PV) and vapor permeation (VP) can be less energy\u2010intensive than distillation\u2010based processes and have proven to be very effective in removing water from azeotropic mixtures. In PV\/VP, separation is based on the solution\u2013diffusion interaction between the dense permselective layer of the membrane and the solvent\/water mixture. This review provides a state\u2010of\u2010the\u2010science analysis of materials used as the selective layer(s) of PV\/VP membranes in removing water from organic solvents. A variety of membrane materials, such as polymeric, inorganic, mixed matrix, and hybrid, have been reported in the literature. A small subset of these is commercially available and highlighted here: poly (vinyl alcohol), polyimides, amorphous perfluoro polymers, NaA zeolites, chabazite zeolites, T\u2010type zeolites, and hybrid silicas. The typical performance characteristics and operating limits of these membranes are discussed. Solvents targeted by the United States Environmental Protection Agency for reclamation are emphasized and ten common solvents are chosen for analysis: acetonitrile, 1\u2010butanol,\n                    <jats:italic>N,N<\/jats:italic>\n                    \u2010dimethyl formamide, ethanol, methanol, methyl isobutyl ketone, methyl tert\u2010butyl ether, tetrahydrofuran, acetone, and 2\u2010propanol. Published 2018. This article is a U.S. Government work and is in the public domain in the USA.\n                  <\/jats:p>","DOI":"10.1002\/jctb.5839","type":"journal-article","created":{"date-parts":[[2018,10,3]],"date-time":"2018-10-03T01:11:10Z","timestamp":1538529070000},"page":"343-365","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":156,"title":["Review: membrane materials for the removal of water from industrial solvents by pervaporation and vapor permeation"],"prefix":"10.1002","volume":"94","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4065-1636","authenticated-orcid":false,"given":"Leland M","family":"Vane","sequence":"first","affiliation":[{"name":"US Environmental Protection Agency  Cincinnati OH USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,11,2]]},"reference":[{"key":"e_1_2_13_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00571"},{"key":"e_1_2_13_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-809270-5.00020-0"},{"key":"e_1_2_13_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/b904997p"},{"key":"e_1_2_13_5_1","volume-title":"Green Chemistry: Theory and Practice","author":"Anastas PT","year":"1998"},{"key":"e_1_2_13_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/es032373g"},{"key":"e_1_2_13_7_1","unstructured":"Overview of the 2015Definition of solid waste final rule(2015). 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