{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T17:51:56Z","timestamp":1787507516338,"version":"build-2736575974"},"reference-count":35,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2022,5,25]],"date-time":"2022-05-25T00:00:00Z","timestamp":1653436800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["acsess.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Env Quality"],"published-print":{"date-parts":[[2022,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A mechanism for carbamazepine (CBZ) sorption by mangrove plant residue\u2013derived biochars pyrolyzed at 200\u2013700 \u00b0C (referred as MPR200\u2013MPR700) was elucidated in this study. The experimental results demonstrated that the dominant sorption mechanism of biochars for CBZ was evolved from partition to adsorption with increasing pyrolysis temperature. The CBZ concentration\u2013dependent contributions of partition and adsorption were controlled by the relative noncarbonized and carbonized fractions of biochars. The partition medium changed from a polymeric aliphatic fraction (mangrove plant residue [MPR]200\u2013MPR400) to a more condensed aromatic phase (MPR500\u2013MPR600), which made the partition less favorable. Meanwhile, the adsorption was selectively regulated by polarity (MPR200\u2013MPR300) and porosity (MPR400\u2013MPR700) for different biochars. A pragmatic model including the sorbent aromaticity index (H\/C) was put forward to predict CBZ sorption to MPR200\u2013MPR700 and other carbonaceous materials reported in the literature. The findings can be helpful in understanding CBZ\u2013biochar interactions and developing effective sorbents (such as biochars) for pollutant sequestration.<\/jats:p>","DOI":"10.1002\/jeq2.20359","type":"journal-article","created":{"date-parts":[[2022,4,23]],"date-time":"2022-04-23T14:18:43Z","timestamp":1650723523000},"page":"745-754","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Mechanism evolution and prediction of carbamazepine sorption by mangrove plant residue\u2013derived biochars"],"prefix":"10.1002","volume":"51","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1114-0741","authenticated-orcid":false,"given":"Lin","family":"Wu","sequence":"first","affiliation":[{"name":"Key Laboratorty of Eco\u2010Geochemistry, Ministry of Natural Resources National Research Center for Geoanalysis (NRCGA)  Beijing 100037 China"},{"name":"China Geological Survey and Hebei Province Key Laboratory of Groundwater 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