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When the donor groups of the ligand are quinolone, thiazole or other similarly conjugated heterocycles, the rhenium complexes are fluorescent, affording complementary and isostructural fluorescent probes to the radioactive <jats:sup>99m<\/jats:sup>Tc analogues. The versatility of the approach has been demonstrated by the preparation of bioconjugates incorporating peptides, biotin, folic acid, thymidine and vitamin B<jats:sub>12<\/jats:sub>. In addition, the unusual photophysical properties observed for rhenium of the [bisthiazole\u2010diamino butane\u2010Re(CO)<jats:sub>3<\/jats:sub><jats:sup>+<\/jats:sup>] derivative [BTBA\u2010Re(CO)<jats:sub>3<\/jats:sub>]<jats:sup>+<\/jats:sup> are discussed.<\/jats:p>","DOI":"10.1002\/jlcr.3164","type":"journal-article","created":{"date-parts":[[2014,1,7]],"date-time":"2014-01-07T04:37:25Z","timestamp":1389069445000},"page":"255-261","source":"Crossref","is-referenced-by-count":43,"title":["Single amino acid chelate complexes of the M(CO)<sub>3<\/sub><sup>+<\/sup> core for correlating fluorescence and radioimaging studies (M\u2009=\u2009<sup>99m<\/sup>Tc or Re)"],"prefix":"10.1002","volume":"57","author":[{"given":"Michael P.","family":"Coogan","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Biology University of Lancaster  Lancaster LA1 4YB UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert P.","family":"Doyle","sequence":"additional","affiliation":[{"name":"Department of Chemistry Syracuse University  Syracuse NY 13244 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John F.","family":"Valliant","sequence":"additional","affiliation":[{"name":"Department of Chemistry McMaster University  Hamilton ON Canada L8S 4K1"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John W.","family":"Babich","sequence":"additional","affiliation":[{"name":"Weill Cornell Medical College  445 E 69th St New York NY 10021"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jon","family":"Zubieta","sequence":"additional","affiliation":[{"name":"Department of Chemistry Syracuse University  Syracuse NY 13244 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2014,1,7]]},"reference":[{"key":"e_1_2_5_2_1","first-page":"127","volume":"5","author":"Alberto R.","year":"2004","journal-title":"CCCII"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1090585"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr1000755"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr980435t"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/a827043z"},{"key":"e_1_2_5_7_1","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1039\/B814903H","volume":"48","author":"Bartholom\u00e4 M.","year":"2009","journal-title":"Chem. 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