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For this reason gradient program for liquid chromatographic separation of 16 color compounds\u2014components of natural blue dyes: elderberry, logwood and indigo\u2014has been developed. Two detector systems were used simultaneously: UV\u2010Vis spectrophotometry (at 280, 445, 520 and 600 nm) and ESI mass spectrometry (positive and negative SIM mode). It was found that fragmentation observed in ESI\u2010MS is affected not only by ion source parameters, but also by chromatographic conditions, especially in case of the less stable substances: cyanidin glucosides, tannic acid, rutin and hematoxylin. Examination of characteristic dissociation pathways of the compounds under investigation after direct admission into ion source or after chromatographic separation allowed to select proper ions for SIM detection and to develop novel and efficient reversed phase high performance liquid chromatographic (RP\u2010HPLC)\u2014UV\u2010Vis\/ESI\u2010MS method for the analysis of natural blue dyes. The procedure was successfully applied for identification of indigotin and carminic acid\u2014main colorants extracted from a fiber taken from the blue\u2013red \u2018Italian\u2019 tapestry (the collection of the National Museum in Warsaw, Poland). Copyright \u00a9 2006 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/jms.1018","type":"journal-article","created":{"date-parts":[[2006,3,30]],"date-time":"2006-03-30T08:46:44Z","timestamp":1143708404000},"page":"613-622","source":"Crossref","is-referenced-by-count":61,"title":["Blue natural organic dyestuffs\u2014from textile dyeing to mural painting. Separation and characterization of coloring matters present in elderberry, logwood and indigo"],"prefix":"10.1002","volume":"41","author":[{"given":"Katarzyna","family":"Pawlak","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Puchalska","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agata","family":"Miszczak","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"El\u017cbieta","family":"Ros\u0142oniec","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maciej","family":"Jarosz","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2006,3,30]]},"reference":[{"key":"e_1_2_6_2_2","volume-title":"Application of Dyestuffs to Textiles, Paper, Leather and Other Materials","author":"Merrit Matthews J","year":"1920"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0959-6526(02)00077-X"},{"key":"e_1_2_6_4_2","volume-title":"Dye Plants and Dyeing","author":"Cannon J","year":"2003"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0891-5849(00)00329-4"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-022X(02)00093-3"},{"key":"e_1_2_6_7_2","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/S0308-8146(96)00222-1","article-title":"Anthocyanins as natural food colours\u2013selected aspects","volume":"58","author":"Briddle P","year":"1997","journal-title":"Food Chem."},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00209-0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(98)00756-9"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/jsfa.910"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1369-703X(02)00219-X"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0308-8146(96)00176-8"},{"key":"e_1_2_6_13_2","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1016\/S0031-9422(00)00091-1","article-title":"Review\u2013application of mass spectrometry for identification and structural studies of flavonoid glycosides","volume":"54","author":"Stobiecki M","year":"2001","journal-title":"Phytochemistry"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/jms.585"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jf00056a027"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/jms.778"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2005.04.073"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/chir.12"},{"key":"e_1_2_6_19_2","volume-title":"The Colourful Past. 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