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In both cases, it led to the formation of only one photoproduct in significant amount: 2\u2010(2,2\u2010difluorobenzo[d][1,3]dioxol\u20104\u2010yl)\u20102\u2010(nitrosomethylene)\u20104\u2010oxobutanenitrile, which has been characterized using Liquid Chromatography \u2010 High Resolution \u2010 Tandem Mass Spectrometry (LC\u2010HR\u2010MS\/MS) coupling. A photolysis pathway has been proposed to rationalize its formation in degassed water. <jats:italic>In vitro<\/jats:italic> bioassays on <jats:italic>Vibrio fischeri<\/jats:italic> bacteria showed that UV\u2013vis irradiation of an aqueous solution of fludioxonil significantly increases its toxicity. Because no other by\u2010product was detected in significant amount, the photoproduct mentioned above may be considered mainly responsible for this increase in toxicity. Grape berries treated with a 50\u2009ppm aqueous solution of fludioxonil were submitted to UV\u2013visible irradiation under laboratory conditions. The fungicide and photoproduct were detected in both skin and flesh of berries, even after they have been rinsed with water. The ability of the photoproduct to pass through the fruit skin is comparable with that of fludioxonil. These results are of concern for consumers because they mean that water tap rinsing does not lead to efficient removing of both compounds. Copyright \u00a9 2015 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/jms.3598","type":"journal-article","created":{"date-parts":[[2015,5,26]],"date-time":"2015-05-26T07:02:58Z","timestamp":1432623778000},"page":"864-869","source":"Crossref","is-referenced-by-count":14,"title":["Structural elucidation and estimation of the acute toxicity of the major UV\u2013visible photoproduct of fludioxonil \u2013 detection in both skin and flesh samples of grape"],"prefix":"10.1002","volume":"50","author":[{"given":"Yannick","family":"Lassalle","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire \u2013 UMR 9168 \u00c9cole Polytechnique  Palaiseau Cedex 91128 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"\u00c9dith","family":"Nicol","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire \u2013 UMR 9168 \u00c9cole Polytechnique  Palaiseau Cedex 91128 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christophe","family":"Genty","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire \u2013 UMR 9168 \u00c9cole Polytechnique  Palaiseau Cedex 91128 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sophie","family":"Bourcier","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire \u2013 UMR 9168 \u00c9cole Polytechnique  Palaiseau Cedex 91128 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"St\u00e9phane","family":"Bouchonnet","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire \u2013 UMR 9168 \u00c9cole Polytechnique  Palaiseau Cedex 91128 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,5,20]]},"reference":[{"key":"e_1_2_6_2_1","unstructured":"European Union 2010"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf5036096"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2013.02.038"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2008.02.087"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)00317-0"},{"key":"e_1_2_6_7_1","doi-asserted-by":"crossref","first-page":"1008","DOI":"10.1093\/jaoac\/86.5.1008","article-title":"Determination of fungicide residues in white grapes for winemaking by gas chromatography with mass spectrometric detection and assessment of matrix effects","volume":"86","author":"Gonzalez C. 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