{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T15:47:22Z","timestamp":1760975242010,"version":"build-2065373602"},"reference-count":33,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2004,6,17]],"date-time":"2004-06-17T00:00:00Z","timestamp":1087430400000},"content-version":"vor","delay-in-days":16,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Mass Spectrom."],"published-print":{"date-parts":[[2004,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Electrospray ionization (ESI) mass spectrometry was applied to the structural analysis of 23 2,6\u2010[bis(alkyloxy)methyl]phenyltin(IV) derivatives. The mass spectra were measured in both polarity modes and multistage tandem mass spectrometric (MS<jats:sup><jats:italic>n<\/jats:italic><\/jats:sup>) measurements were performed on the ion trap analyser for positively charged tin\u2010containing ions. The sum of complementary ions observed in the positive\u2010ion mode (i.e. [M\u2013R<jats:sup>3<\/jats:sup>]<jats:sup>+<\/jats:sup> ion) and in the negative\u2010ion mode (i.e. [R<jats:sup>3<\/jats:sup>]<jats:sup>\u2212<\/jats:sup> ion) permits molecular mass determination in spite of the fact that the molecular adducts were often missing even in the first\u2010order mass spectra. The subsequent fragmentation of [M\u2013R<jats:sup>3<\/jats:sup>]<jats:sup>+<\/jats:sup> ions studied by MS<jats:sup><jats:italic>n<\/jats:italic><\/jats:sup> and the correlation of observed fragment ions with the expected structures of synthesized organotin(IV) compounds allowed us to understand the fragmentation behaviour and the mechanism of the ion formation for studied compounds. The typical neutral losses are alkenes, alcohols and aldehydes. The fragmentation pattern of one selected compound was supported by MS<jats:sup><jats:italic>n<\/jats:italic><\/jats:sup> measurements of an isotopically labelled analogue to confirm unusual ion\u2013molecule reactions of some fragment ions with water in the ion trap. Copyright \u00a9 2004 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/jms.628","type":"journal-article","created":{"date-parts":[[2004,6,17]],"date-time":"2004-06-17T06:00:37Z","timestamp":1087452037000},"page":"621-629","source":"Crossref","is-referenced-by-count":26,"title":["Structural analysis of 2,6\u2010[bis(alkyloxy)methyl]\u2010phenyltin derivatives using electrospray ionization mass spectrometry"],"prefix":"10.1002","volume":"39","author":[{"given":"Lenka","family":"Kol\u00e1\u0159ov\u00e1","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michal","family":"Hol\u010dapek","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roman","family":"Jambor","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Libor","family":"Dost\u00e1l","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Milan","family":"N\u00e1dvorn\u00edk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ale\u0161","family":"R\u016f\u017ei\u010dka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2004,6,17]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"crossref","DOI":"10.1002\/0470857188","volume-title":"The Chemistry of Organic Germanium, Tin and Lead Compounds","author":"Rappoport Z","year":"2002"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.220.4595.365"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.302"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-4938-9"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000813w"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/om960895h"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00006a031"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(93)80454-J"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0103714"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000588i"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(01)00596-5"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.401"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/om020361i"},{"key":"e_1_2_6_15_2","first-page":"527","volume-title":"Electrospray Ionization Mass Spectrometry","author":"Gatlin CL","year":"1997"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/mas.1280140203"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)00603-4"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1097-0231(20001030)14:20<1881::AID-RCM107>3.0.CO;2-I"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac00195a021"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1007\/s002160050082"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.1290071108"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0739(199603)10:2<125::AID-AOC491>3.0.CO;2-1"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0739(199912)13:12<881::AID-AOC948>3.0.CO;2-S"},{"key":"e_1_2_6_24_2","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1039\/B007321K","article-title":"Determination of tributyltin by automated in\u2010tube solid\u2010phase microextraction coupled with HPLC\u2013ES\u2010MS","volume":"16","author":"Wu JC","year":"2001","journal-title":"J. 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