{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,11]],"date-time":"2026-03-11T03:05:23Z","timestamp":1773198323394,"version":"3.50.1"},"reference-count":36,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T00:00:00Z","timestamp":1768953600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T00:00:00Z","timestamp":1768953600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J Mass Spectrom"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Direct\u2010infusion ESI\/IT\u2010MS\/MS was previously employed to characterize grape anthocyanins that share the same nominal mass but differ in elemental composition. Subsequently, Q\u2010TOF coupled with LC\u2010Chip enabled the complete anthocyanin fingerprint of a single sample to be obtained in under 5\u2009min. In this study, a comprehensive UHPLC\/Q\u2010TOF investigation of anthocyanins in three red\u2010berry fruits (blueberry, raspberry, and two fungal\u2010resistant red grape varieties) was performed. In total, 35 anthocyanins were identified. Only two were found in all three fruits, Cy and Pn 3\u2010\n                    <jats:italic>O<\/jats:italic>\n                    \u2010hexosides. The grape berries exhibit high levels of diglucosides, while only raspberries contain Pg derivatives and several di\u2010 and trisaccharide anthocyanins. Blueberry uniquely accumulated Pn\u2010malonylhexoside and arabinosyl anthocyanins, and a difference between the two species was found, as\n                    <jats:italic>cv<\/jats:italic>\n                    Biloxi (southern highbush) contained acetyl\u2010 and\n                    <jats:italic>p<\/jats:italic>\n                    \u2010coumaroyl glucosides not found in\n                    <jats:italic>cv<\/jats:italic>\n                    Titan (rabbiteye), alongside a preponderance of B\u2010ring tri\u2010substituted anthocyanins. Additionally, in blueberry two isobaric anthocyanins (Pn\u2010hexoside and Mv\u2010arabinoside, MF C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>23<\/jats:sub>\n                    O\n                    <jats:sub>11<\/jats:sub>\n                    ) were characterized. Sophoroside and rutinoside anthocyanins were found only in the raspberry, where Pn\u2010hexosyl\u2010rutinoside, Cy\u20103\u2010hexosyl\u2010sophoroside, and a Cy\u2010rutinoside isomer were characterized for the first time. Findings of the study increase the knowledge on these varieties as potential sources of nutraceuticals and natural colorants, also expanding the HR\u2010MS\/MS dataset beneficial for their characterization in other fruit varieties.\n                  <\/jats:p>","DOI":"10.1002\/jms.70030","type":"journal-article","created":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T14:51:02Z","timestamp":1769007062000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Comprehensive Study of Anthocyanins in Two Fungal\u2010Resistant Grape Varieties, Blueberry and Raspberry, by High\u2010Resolution Mass Spectrometry"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4005-7012","authenticated-orcid":false,"given":"M.","family":"De\u00a0Rosso","sequence":"first","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K.","family":"Muniyandi","sequence":"additional","affiliation":[{"name":"Department of Postharvest and Food Sciences, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K.","family":"Kumar","sequence":"additional","affiliation":[{"name":"Department of Postharvest and Food Sciences, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"T.","family":"N'gambi","sequence":"additional","affiliation":[{"name":"Department of Postharvest and Food Sciences, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"N.","family":"Dai","sequence":"additional","affiliation":[{"name":"Department of Vegetable Field Crop Research, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G.","family":"Tamir","sequence":"additional","affiliation":[{"name":"Department of Vegetable Field Crop Research, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"R.","family":"Carraro","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"L.","family":"Tarricone","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G.","family":"Masi","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"S.","family":"Roccotelli","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"Gardiman","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A.","family":"Panighel","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"L.","family":"Sansone","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"I.","family":"Maoz","sequence":"additional","affiliation":[{"name":"Department of Postharvest and Food Sciences, Agricultural Research Organization Volcani Institute  Rishon LeZion Israel"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0872-9675","authenticated-orcid":false,"given":"R.","family":"Flamini","sequence":"additional","affiliation":[{"name":"Council for Agricultural Research and Economics \u2010 Research Center for Viticulture &amp; Enology (CREA\u2010VE)  Conegliano Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,1,21]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fbio.2023.103050"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tifs.2017.05.015"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scienta.2023.112318"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.3390\/metabo12040363"},{"key":"e_1_2_7_6_1","unstructured":"European Commission 2018 \u201cCommission Implementing Regulation (EU) 2018\/1981 of 13 December 2018 renewing the approval of the active substances copper compounds as candidates for substitution in accordance with Regulation (EC) No 1107\/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market and amending the Annex to Commission Implementing Regulation (EU) No 540\/2011 \u201d (Text with EEA relevance)."},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scienta.2016.03.016"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf0260747"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules17021571"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00217\u2010019\u201003355\u20104"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1155\/2015\/350259"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf048068b"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1080\/10942912.2015.1107844"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/jms.778"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodres.2017.01.024"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2011.10.045"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.5344\/ajev.2000.51.1.55"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2009.04.032"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.3390\/beverages3040056"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfca.2021.104051"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf049450r"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.freeradbiomed.2015.10.400"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/s002170050371"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00122\u2010012\u20101957\u20109"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijgfs.2021.100316"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/JF00056A027"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf011261a"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf048939h"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021\u20109673(99)00256\u20103"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf981242"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2024.138778"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.4199"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11306\u2010013\u20100530\u20100"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2011.08.022"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.3c09668"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2008.03.067"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1080\/10942912.2022.2075380"}],"container-title":["Journal of Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jms.70030","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/jms.70030","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jms.70030","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T06:38:17Z","timestamp":1773124697000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jms.70030"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,21]]},"references-count":36,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/jms.70030"],"URL":"https:\/\/doi.org\/10.1002\/jms.70030","archive":["Portico"],"relation":{},"ISSN":["1076-5174","1096-9888"],"issn-type":[{"value":"1076-5174","type":"print"},{"value":"1096-9888","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,21]]},"assertion":[{"value":"2025-09-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-02","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70030"}}