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Mass Spectrom."],"published-print":{"date-parts":[[2005,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Electrospray ionization mass spectrometry was used for the analysis of functionalized rhenium clusters such as [Re<jats:sub>6<\/jats:sub>Se<jats:sub>8<\/jats:sub>(<jats:italic>o<\/jats:italic>\u2010Me<jats:sub>2<\/jats:sub>TTFPPh<jats:sub>2<\/jats:sub>)<jats:sub>6<\/jats:sub>]<jats:sup>2+<\/jats:sup> (<jats:bold>1<\/jats:bold>), {Re<jats:sub>6<\/jats:sub>Se<jats:sub>8<\/jats:sub>[(<jats:italic>o<\/jats:italic>\u2010Me<jats:sub>2<\/jats:sub>TTF)<jats:sub>2<\/jats:sub>PPh]<jats:sub>6<\/jats:sub>}<jats:sup>2+<\/jats:sup> (<jats:bold>2<\/jats:bold>) and [Re<jats:sub>6<\/jats:sub>Se<jats:sub>8<\/jats:sub>(MePPh<jats:sub>2<\/jats:sub>)<jats:sub>6<\/jats:sub>]<jats:sup>2+<\/jats:sup> (<jats:bold>3<\/jats:bold>). The high\u2010resolution mass spectra of the intact clusters, performed in dichloromethane, confirm the identification of the compounds by comparison with the theoretical isotopic distributions. Low\u2010resolution full\u2010scan mass spectra recorded at increasing desolvation cone voltage values allow the study of the intrinsic reactivity of ionic species. The survival yield curves illustrating the bimolecular reactivity of <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> suggest that a bisdimethyltetrathiafulvalene(phenyl)phosphine ligand increases the stability of the functionalized ML<jats:sub>6<\/jats:sub><jats:sup>2+<\/jats:sup> cluster <jats:bold>2<\/jats:bold>. In the case of the <jats:bold>3<\/jats:bold>, instead of loss of a neutral ligand, ligand exchange is observed either with traces of water present in dichloromethane or with acetonitrile used as solvent. Copyright \u00a9 2004 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/jms.774","type":"journal-article","created":{"date-parts":[[2004,12,7]],"date-time":"2004-12-07T06:16:17Z","timestamp":1102400177000},"page":"60-65","source":"Crossref","is-referenced-by-count":10,"title":["Electrospray ionization mass spectrometry of organic\u2013inorganic materials: identification and gas\u2010phase reactivity of functionalized octahedral rhenium(III) clusters"],"prefix":"10.1002","volume":"40","author":[{"given":"David","family":"Rondeau","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sandrine","family":"Perruchas","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Narcis","family":"Avarvari","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Patrick","family":"Batail","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Karoly","family":"V\u00e9key","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2004,12,7]]},"reference":[{"key":"e_1_2_5_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr980058k"},{"key":"e_1_2_5_3_2","unstructured":"PerruchasS Synthe\u00e8se de mat\u00e9riaux mol\u00e9culaires cristallins engageant des clusters octa\u00e9driques de rhe\u00e9nium chalcog\u00e9n\u00e9s. Electrocristallisation confin\u00e9 et polymorphisme. Th\u00e9se de l'\u00c9cole Polytechnique soutenue le 12 Septembre2003."},{"key":"e_1_2_5_4_2","article-title":"Three Dimensional Multi\u2010Electron Donors Based on TTF\u2010Phosphine and Ferrocene\u2010Phosphine Hybrid Complexes of an Hexarhenium (III) Octahedral Cluster Core","author":"Perruchas S","journal-title":"Inorg. 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