{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T12:43:40Z","timestamp":1772973820021,"version":"3.50.1"},"reference-count":51,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2024,10,23]],"date-time":"2024-10-23T00:00:00Z","timestamp":1729641600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22268019"],"award-info":[{"award-number":["22268019"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["scijournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J Sci Food Agric"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:sec><jats:title>BACKGROUND<\/jats:title><jats:p>The conversion of biomass into high value\u2010added platform compounds is an important method of biomass utilization. The conversion of hemicellulose represented by xylan into furfural can not only reduce the consumption of fossil fuels, but also promotes the development and utilization of non\u2010edible biomass resources. In this study, a bifunctional solid\u2010acid catalyst prepared from agricultural and forestry waste <jats:italic>Pueraria<\/jats:italic> (<jats:italic>P. eduli)<\/jats:italic> Residues was used to convert xylan into furfural in a biphasic system.<\/jats:p><\/jats:sec><jats:sec><jats:title>RESULTS<\/jats:title><jats:p>In this study, <jats:italic>P. eduli<\/jats:italic> Residues was used as raw material to prepare a <jats:italic>P. eduli<\/jats:italic> Residues\u2010based carbon solid\u2010acid catalyst (PR\/C\u2010SO<jats:sub>3<\/jats:sub>H\u2010Fe) by one\u2010step sulfonation carbonization and impregnation. The catalyst catalyzes the conversion of xylan to furfural in a biphasic system (2\u2010methyltetrahydrofuran\/water). The physicochemical properties of the catalysts were characterized by X\u2010ray powder diffraction, scanning electron microscopy, differential thermogravimetric analysis, Brunauer\u2013Emmett\u2013Teller surface area, Fourier transform infrared spectroscopy and ammonia temperature\u2010programmed desorption. Subsequently, the experimental conditions were studied and optimized, such as metal species, iron ion concentration, reaction time and temperature, volume ratio of organic phase to water phase and ratio of substrate to catalyst. The results showed that under conditions of 160\u2009\u00b0C, 50\u2009mg catalyst, 100\u2009mg xylan and 7\u2009mL reaction solvent, the yield of furfural could reach 78.94% after 3\u2009h of reaction.<\/jats:p><\/jats:sec><jats:sec><jats:title>CONCLUSION<\/jats:title><jats:p>This study provides an effective research method for the conversion of xylan into furfural, and provides a reference for the catalytic conversion and utilization of hemicellulose in agricultural and forestry biomass. It also provides a feasible method for the resource utilization of agricultural and forestry waste. \u00a9 2024 Society of Chemical Industry.<\/jats:p><\/jats:sec>","DOI":"10.1002\/jsfa.13976","type":"journal-article","created":{"date-parts":[[2024,10,23]],"date-time":"2024-10-23T07:43:47Z","timestamp":1729669427000},"page":"2002-2011","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Furfural production from xylan using a <scp><i>Pueraria<\/i><\/scp> Residues carbon\u2010based solid\u2010acid catalyst"],"prefix":"10.1002","volume":"105","author":[{"given":"Xiangtong","family":"Gai","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Jishou University  Jishou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Ding","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Jishou University  Jishou 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