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This present paper reports the effect of the CSP structural change on chiral selectivity \u03b1. The enantiomers of a series of compounds were chromatographed using ethanol or 2\u2010propanol in various concentrations as mobile\u2010phase modifier and the \u03b1 values were determined. Changes of \u03b1 were observed for some enantiomeric pairs when ethanol and 2\u2010propanol concentrations were varied. These data correlate with previous findings on the structural changes of the CSP. Not every enantiomeric pair showed changes in \u03b1 as the alcohol concentration was varied, indicating that the chiral selectivity depends not only on the CSP's structure, but also on the structures of the analytes.<\/jats:p>","DOI":"10.1002\/jssc.200401892","type":"journal-article","created":{"date-parts":[[2004,12,22]],"date-time":"2004-12-22T04:56:03Z","timestamp":1103691363000},"page":"189-192","source":"Crossref","is-referenced-by-count":13,"title":["Selectivity of amylose tris(3,5\u2010dimethylphenyl\u2010carbamate) chiral stationary phase as a function of its structure altered by changing concentration of ethanol or 2\u2010propanol mobile\u2010phase modifier"],"prefix":"10.1002","volume":"28","author":[{"given":"Roy","family":"Helmy","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Wang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,2]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(94)80400-1"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.68.3289"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980504)37:8<1020::AID-ANIE1020>3.0.CO;2-5"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1998-1675"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0014-827X(02)01242-9"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00950-X"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)94466-8"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)93965-7"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(94)85121-2"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-022X(01)00148-8"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(95)00891-8"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(94)89142-7"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(99)00733-5"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00862-1"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(96)00463-3"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0801(200006)14:4<227::AID-BMC971>3.0.CO;2-Q"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac0103672"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)01262-7"},{"key":"e_1_2_1_20_2","unstructured":"L.R.Snyder J.J.Kirkland Introduction to Modern Liquid Chromatography Wiley New York NY 1974 pp. 27\u201328."},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)95466-4"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(95)00686-9"}],"container-title":["Journal of Separation Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fjssc.200401892","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.200401892","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T12:56:06Z","timestamp":1760878566000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jssc.200401892"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,2]]},"references-count":21,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2005,2]]}},"alternative-id":["10.1002\/jssc.200401892"],"URL":"https:\/\/doi.org\/10.1002\/jssc.200401892","archive":["Portico"],"relation":{},"ISSN":["1615-9306","1615-9314"],"issn-type":[{"value":"1615-9306","type":"print"},{"value":"1615-9314","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,2]]}}}