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The influence of mobile phase composition and column temperatures from 0\u00b0C to 40\u00b0C on the separations were investigated. The mobile phases were methanol\/water or ACN\/water at a flow rate of 0.8 mL\/min with UV detection at 230 or 210 nm. Epoxiconazole, terallethrin, benalaxyl, and diclofop\u2010methyl were observed to obtain the baseline separation under suitable conditions and other pesticides pyriproxyfen, lactofen, and quizalofop\u2010ethyl were separated partially. The retention factors (<jats:italic>k<\/jats:italic>) and selectivity factor (\u03b1) for the enantiomers of most investigated pesticides decreased upon increasing the temperature except for the selectivity factors (\u03b1) of pyriproxyfen in methanol\/water. The ln \u03b1\u20131\/<jats:italic>T<\/jats:italic> plots for racemic chiral pesticides were linear at the range of 0\u201340 except for that of pyriproxyfen enantiomers in methanol\/water and the chiral separations were controlled by enthalpy. Better separations were not always at low temperature. The elution orders of the eluting enantiomers were determined by a circular dichroism (CD) detector.<\/jats:p>","DOI":"10.1002\/jssc.200600255","type":"journal-article","created":{"date-parts":[[2007,2,13]],"date-time":"2007-02-13T07:22:45Z","timestamp":1171351365000},"page":"310-321","source":"Crossref","is-referenced-by-count":36,"title":["Enantiomeric separation of chiral pesticides by high performance liquid chromatography on cellulose tris\u20103,5\u2010dimethyl carbamate stationary phase under reversed phase conditions"],"prefix":"10.1002","volume":"30","author":[{"given":"Qin","family":"Tian","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chunguang","family":"Lv","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liping","family":"Ren","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing","family":"Qiu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhiqiang","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2007,2,13]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2003.10.026"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1096-9063(199601)46:1<3::AID-PS337>3.0.CO;2-J"},{"key":"e_1_2_1_4_2","first-page":"366","volume":"35","author":"Nestler H. 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