{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,25]],"date-time":"2026-07-25T02:17:57Z","timestamp":1784945877257,"version":"3.55.0"},"reference-count":19,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2012,12,11]],"date-time":"2012-12-11T00:00:00Z","timestamp":1355184000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2013,1]]},"abstract":"<jats:p>A simple chiral analytical method was developed for the enantiomeric determination of cyflumetofen in cucumber, tomato, and apple by normal\u2010phase <jats:styled-content style=\"fixed-case\">HPLC<\/jats:styled-content>. The effects of mobile phase composition and column temperature on the enantioseparation were evaluated. Excellent separation was achieved at 25\u00b0C on a <jats:styled-content style=\"fixed-case\">C<\/jats:styled-content>hiralpak <jats:styled-content style=\"fixed-case\">AD<\/jats:styled-content>\u2010<jats:styled-content style=\"fixed-case\">H<\/jats:styled-content> column, with a mixture of <jats:italic>n<\/jats:italic>\u2010hexane and 2\u2010propanol (95:5, v\/v) as mobile phase at a flow rate of 1.0 mL\/min detecting at 234 nm. The resolution of cyflumetofen enantiomers was up to 5.5. The elution order of the enantiomers was determined by an online <jats:styled-content style=\"fixed-case\">OR<\/jats:styled-content>\u20102090 detector, which was performed under the same chromatographic conditions. The first eluted enantiomer was (\u2013)\u2010cyflumetofen and the second eluted one was (+)\u2010cyflumetofen. The method was validated for linearity, repeatability, accuracy, <jats:styled-content style=\"fixed-case\">LOD<\/jats:styled-content>, and <jats:styled-content style=\"fixed-case\">LOQ<\/jats:styled-content>. <jats:styled-content style=\"fixed-case\">LOD<\/jats:styled-content> ranged from 0.1 to 0.15 mg\/kg, with the <jats:styled-content style=\"fixed-case\">LOD<\/jats:styled-content> varying from 0.33 to 0.5 mg\/kg for each enantiomer, respectively. The average recoveries of the pesticide ranged from 71.4 to 102.0% at all fortification levels. The precision values associated with the analytical method, expressed as <jats:styled-content style=\"fixed-case\">RSD<\/jats:styled-content> values, were below 14.8% in all matrices. The method was then successfully applied to detect cyflumetofen enantiomers in real samples.<\/jats:p>","DOI":"10.1002\/jssc.201200636","type":"journal-article","created":{"date-parts":[[2012,12,11]],"date-time":"2012-12-11T10:14:07Z","timestamp":1355220847000},"page":"225-231","source":"Crossref","is-referenced-by-count":14,"title":["Chiral determination of a novel acaricide cyflumetofen enantiomers in cucumber, tomato, and apple by <scp>HPLC<\/scp>"],"prefix":"10.1002","volume":"36","author":[{"given":"Xiu","family":"Chen","sequence":"first","affiliation":[{"name":"Institute of Plant Protection, Chinese Academy of Agricultural Sciences Key Laboratory of Pesticide Chemistry and Application Ministry of Agriculture  Beijing P. R. 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