{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,29]],"date-time":"2025-10-29T13:23:12Z","timestamp":1761744192097,"version":"build-2065373602"},"reference-count":22,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2015,11,3]],"date-time":"2015-11-03T00:00:00Z","timestamp":1446508800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2015,12]]},"abstract":"<jats:p>By using density functional theory, we studied the interaction process between barbital and 2\u2010vinyl\u20104,6\u2010diamino\u20101,3,5\u2010triazine in acetonitrile at 333 K. Barbital and 2\u2010vinyl\u20104,6\u2010diamino\u20101,3,5\u2010triazine were used as the template and functional monomer, respectively. The molecularly imprinted polymer microspheres containing barbital and 2\u2010vinyl\u20104,6\u2010diamino\u20101,3,5\u2010triazine were synthesized through precipitation polymerization. After removing the template molecule barbital, the average diameter of the obtained molecularly imprinted polymers was 1.45 \u03bcm. By optimizing the molar ratio of barbital and the 2\u2010vinyl\u20104,6\u2010diamino\u20101,3,5\u2010triazine, the resulting molecularly imprinted polymers showed the highest adsorption for the barbital. The analysis of the Scatchard plot revealed that the dissociation constant (<jats:italic>K<\/jats:italic><jats:sub>d<\/jats:sub>) and apparent maximum adsorption quantity (<jats:italic>Q<\/jats:italic><jats:sub>max<\/jats:sub>) of the molecularly imprinted polymers were 30.69 mg\/L and 8.68 mg\/g, respectively. The study of selective adsorption showed that molecularly imprinted polymers exhibited higher selectivity for barbtital than that for 1,3\u2010dimethyl barbituric acid and pentobarbital. Herein, the studies can provide theoretical and experimental references for the barbital\u2010imprinted system.<\/jats:p>","DOI":"10.1002\/jssc.201500891","type":"journal-article","created":{"date-parts":[[2015,9,30]],"date-time":"2015-09-30T05:00:37Z","timestamp":1443589237000},"page":"4105-4110","source":"Crossref","is-referenced-by-count":9,"title":["Theoretical and experimental studies on the performances of barbital\u2010imprinted systems"],"prefix":"10.1002","volume":"38","author":[{"given":"Jun\u2010Bo","family":"Liu","sequence":"first","affiliation":[{"name":"College of Resource and Environmental Science Jilin Agricultural University  Changchun China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yan","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Resource and Environmental Science Jilin Agricultural University  Changchun China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ting\u2010Ting","family":"Su","sequence":"additional","affiliation":[{"name":"College of Resource and Environmental Science Jilin Agricultural University  Changchun China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo","family":"Li","sequence":"additional","affiliation":[{"name":"Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering Hebei United University  Tangshan Hebei China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shan\u2010Shan","family":"Tang","sequence":"additional","affiliation":[{"name":"College of Resource and Environmental Science Jilin Agricultural University  Changchun China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rui\u2010Fa","family":"Jin","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Chifeng University  Chifeng China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,11,3]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jchromb.2013.07.006"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2011.08.022"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2014.01.035"},{"key":"e_1_2_8_5_1","first-page":"945","volume":"36","author":"Wang Y.","year":"2015","journal-title":"Chem. 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