{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T00:17:58Z","timestamp":1760919478153,"version":"build-2065373602"},"reference-count":42,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2016,7,4]],"date-time":"2016-07-04T00:00:00Z","timestamp":1467590400000},"content-version":"vor","delay-in-days":3,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["G12MD007601, U54MD007584, P20GM103466"],"award-info":[{"award-number":["G12MD007601, U54MD007584, P20GM103466"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2016,7]]},"abstract":"<jats:p>The current theory of programmed temperature gas chromatography considers that solutes are focused by the stationary phase at the column head completely and does not explicitly recognize the different effects of initial temperature (<jats:italic>T<\/jats:italic><jats:sub>o<\/jats:sub>) and heating rate (<jats:italic>r<\/jats:italic><jats:sub>T<\/jats:sub>) on the retention time or temperature of a homologue series. In the present study, <jats:italic>n<\/jats:italic>\u2010alkanes, 1\u2010alkenes, 1\u2010alkyl alcohols, alkyl benzenes, and fatty acid methyl esters standards were used as model chemicals and were separated on two nonpolar columns, one moderately polar column and one polar column. Effects of T<jats:sub>o<\/jats:sub> and r<jats:sub>T<\/jats:sub> on the retention of nonstationary phase focusing solutes can be explicitly described with isothermal and cubic equation models, respectively. When the solutes were in the stationary phase focusing status, the single\u2010retention behavior of solutes was observed. It is simple, dependent upon <jats:italic>r<\/jats:italic><jats:sub>T<\/jats:sub> only and can be well described by the cubic equation model that was visualized through four sequential slope analyses. These observed dual\u2010 and single\u2010retention behaviors of solutes were validated by various experimental data, physical properties, and computational simulation.<\/jats:p>","DOI":"10.1002\/jssc.201600236","type":"journal-article","created":{"date-parts":[[2016,5,31]],"date-time":"2016-05-31T05:18:44Z","timestamp":1464671924000},"page":"2785-2795","source":"Crossref","is-referenced-by-count":1,"title":["Phenomenon of dual\u2010 and single\u2010retention behaviors of solutes and its validation by computational simulation in linear programmed temperature gas chromatography"],"prefix":"10.1002","volume":"39","author":[{"given":"Liejun","family":"Wu","sequence":"first","affiliation":[{"name":"Department of Molecular Biosciences and Bioengineering University of Hawaii at Manoa  Honolulu HI USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaojuan","family":"Duan","sequence":"additional","affiliation":[{"name":"Qingdao Entry\u2010Exit Inspection and Quarantine Bureau  Qingdao China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chuanyu","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Oceanography,\u00a0Chinese Academy of Sciences  Qingdao China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guangxiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Office of Biostatistics and Quantitative Health Sciences, John A. Burns School of Medicine University of Hawaii at Manoa  Honolulu HI USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qing X.","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Molecular Biosciences and Bioengineering University of Hawaii at Manoa  Honolulu HI USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,7,4]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac60163a009"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac60160a001"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed039p569"},{"key":"e_1_2_8_5_1","unstructured":"Giddings J. C. Gas chromatography.Academic Press New York1962."},{"volume-title":"Programmed temperature gas chromatography","year":"1966","author":"Harris W. E.","key":"e_1_2_8_6_1"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/jhrc.1240160108"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(95)00692-3"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(96)00961-2"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(99)00366-0"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac000378f"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(99)00158-2"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2008.10.092"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2008.11.049"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527632145"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)95980-1"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00146a020"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)89512-1"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1093\/chromsci\/45.8.492"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.02.032"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-007-1528-0"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2010.05.037"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.02.023"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2003.10.007"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.2116\/analsci.24.419"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2005.05.105"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2007.07.057"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/jhrc.1240081118"},{"key":"e_1_2_8_29_1","unstructured":"Agilent https:\/\/www.agilent.com\/cs\/library\/usermanuals\/public\/5958-9468_041007.pdf. (last time accessed: May 9 2016)"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2007.03.029"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)00932-1"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200301505"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.07.077"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.08.071"},{"volume-title":"Basic relationships of gas chromatography","year":"1993","author":"Ettre L. S.","key":"e_1_2_8_35_1"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)80220-4"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)94099-8"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.555942"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.556054"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.3390\/60400370"},{"key":"e_1_2_8_41_1","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1365\/s10337-003-0013-y","article-title":"Relationships between retention data of benzene and chlorobenzenes with their physico\u2010chemical properties and topological indices","volume":"58","author":"Santiuste J. M.","year":"2003","journal-title":"Chromatographia"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)00448-5"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.05.021"}],"container-title":["Journal of Separation Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fjssc.201600236","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.201600236","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T08:45:21Z","timestamp":1760863521000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jssc.201600236"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,7]]},"references-count":42,"journal-issue":{"issue":"14","published-print":{"date-parts":[[2016,7]]}},"alternative-id":["10.1002\/jssc.201600236"],"URL":"https:\/\/doi.org\/10.1002\/jssc.201600236","archive":["Portico"],"relation":{},"ISSN":["1615-9306","1615-9314"],"issn-type":[{"type":"print","value":"1615-9306"},{"type":"electronic","value":"1615-9314"}],"subject":[],"published":{"date-parts":[[2016,7]]}}}