{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T23:31:25Z","timestamp":1790379085568,"version":"4.1.0"},"reference-count":40,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2017,8,28]],"date-time":"2017-08-28T00:00:00Z","timestamp":1503878400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Environmental Protection Agency of Ireland","award":["2014-RE-MS-2"],"award-info":[{"award-number":["2014-RE-MS-2"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2017,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Due to new European legislation, products going to waste are subject to \u2018low persistent organic pollutant concentration limits\u2019. Concentrations of restricted brominated flame retardants in waste products must be determined. A rapid extraction and clean\u2010up method was developed for determination of brominated flame retardants in various plastics and textiles. The optimised method used vortexing and ultrasonication in dichloromethane followed by sulfuric acid clean\u2010up to determine target compounds. Poly\u2010brominated diphenyl ethers were determined by gas chromatography with mass spectrometry and hexabromocyclododecane by liquid chromatography with tandem mass spectrometry. Good recoveries of target analytes were obtained after three extraction cycles. The method was validated using poly\u2010propylene and poly\u2010ethylene certified reference materials as well as previously characterised textiles, expanded and extruded poly\u2010styrene samples. Measured concentrations of target compounds showed good agreement with the certified values indicating good accuracy and precision. Clean extracts provided low noise levels resulting in low limits of quantification (0.8\u20131.5\u00a0ng\/g for poly\u2010brominated diphenyl ethers and 0.3\u00a0ng\/g for \u03b1\u2010, \u03b2\u2010 and \u03b3\u2010hexabromocyclododecane). The developed method was applied successfully to real consumer products entering the waste stream and it provided various advantages over traditional methods, including reduced analysis time, solvent consumption, minimal sample contamination and high sample throughput, which is crucial to comply with the implemented legislation.<\/jats:p>","DOI":"10.1002\/jssc.201700497","type":"journal-article","created":{"date-parts":[[2017,7,27]],"date-time":"2017-07-27T04:22:34Z","timestamp":1501129354000},"page":"3873-3881","source":"Crossref","is-referenced-by-count":40,"title":["A rapid method for the determination of brominated flame retardant concentrations in plastics and textiles entering the waste stream"],"prefix":"10.1002","volume":"40","author":[{"given":"Mohamed Abou\u2010Elwafa","family":"Abdallah","sequence":"first","affiliation":[{"name":"School of Geography, Earth and Environmental Sciences University of Birmingham  Edgbaston West Midlands United Kingdom"},{"name":"Department of Analytical Chemistry, Faculty of Pharmacy Assiut University  Assiut Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel S.","family":"Drage","sequence":"additional","affiliation":[{"name":"School of Geography, Earth and Environmental Sciences University of Birmingham  Edgbaston West Midlands United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Sharkey","sequence":"additional","affiliation":[{"name":"School of Physics National University of Ireland Galway, University Road  Galway Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harald","family":"Berresheim","sequence":"additional","affiliation":[{"name":"School of Physics National University of Ireland Galway, University Road  Galway Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stuart","family":"Harrad","sequence":"additional","affiliation":[{"name":"School of Geography, Earth and Environmental Sciences University of Birmingham  Edgbaston West Midlands United Kingdom"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,8,28]]},"reference":[{"key":"e_1_2_7_2_1","unstructured":"https:\/\/www.efsa.europa.eu\/en\/topics\/topic\/brominated-flame-retardants(last time accessed 5 April 2017)."},{"key":"e_1_2_7_3_1","unstructured":"http:\/\/chm.pops.int\/Programmes\/NewPOPs\/The9newPOPs\/tabid\/672\/language\/en-US\/Default.aspx(last time accessed December 12 2010)."},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","unstructured":"http:\/\/www.env-health.org\/news\/latest-news\/article\/global-ban-of-flame-retardant-hbcd(last time accessed June 6 2014).","DOI":"10.1021\/cen-09119-notw3"},{"key":"e_1_2_7_5_1","unstructured":"http:\/\/chm.pops.int\/Portals\/0\/download.aspx?d = UNEP-POPS-POPRC.9-2.English.pdf(last time accessed November 15 2012)."},{"key":"e_1_2_7_6_1","unstructured":"http:\/\/www.edn.com\/electronics-news\/4326700\/ROHS-DecaBDE-exemption-ending(last time accessed February 8 2013)."},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2015.10.121"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2006.01.019"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envint.2008.04.001"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2015.01.007"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2009.12.016"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2016.03.031"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10661-012-2565-5"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2004.08.076"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2011.11.001"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2011.07.068"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/es060570k"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2007.09.043"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.200800479"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2008.06.005"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/es101503r"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envint.2012.05.003"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201300579"},{"key":"e_1_2_7_24_1","first-page":"17","article-title":"Commission regulation (EU) 2016\/460 of 30 March 2016 amending Annexes IV and V to regulation No 850\/2004 of the European Parliament and of the Council on persistent organic pollutants.","volume":"80","author":"European Commission","year":"2016","journal-title":"Off. 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