{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T18:48:21Z","timestamp":1790189301589,"version":"4.1.0"},"reference-count":30,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2018,1,26]],"date-time":"2018-01-26T00:00:00Z","timestamp":1516924800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100008132","name":"Universidade Federal de Pernambuco","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006582","name":"Centro de Tecnologias Estrat\u00e9gicas do Nordeste","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006582","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005671","name":"Funda\u00e7\u00e3o de Apoio \u00e0 Pesquisa e \u00e0 Inova\u00e7\u00e3o Tecnol\u00f3gica do Estado de Sergipe","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100005671","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2018,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The metal\u2013organic framework [(La<jats:sub>0.9<\/jats:sub>Sm<jats:sub>0.1<\/jats:sub>)<jats:sub>2<\/jats:sub>(DPA)<jats:sub>3<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>3<\/jats:sub>]<jats:sub>\u221e<\/jats:sub> was synthetized and characterized by X\u2010ray diffractometry, differential thermogravimetric analysis, and infrared spectroscopy. The material was tested for the development and validation of a matrix solid\u2010phase dispersion procedure for extraction of atrazine, bifenthrin, bromuconazole, clofentezine, fenbuconazole, flumetralin, procymidone, and pirimicarb, from peppers, with analysis using gas chromatography with mass spectrometry in the selected ion monitoring mode. The method developed was linear over the range tested (50.0\u20131000.0\u00a0\u03bcg\/kg for procymidone and 200.0\u20131000.0\u00a0\u03bcg\/kg for all other pesticides), with correlation coefficients ranging from 0.9930 to 0.9992. Experiments were carried out at 250.0, 500.0, and 1000.0\u00a0\u03bcg\/kg fortification levels, and resulted in recoveries in the range of 52.7\u2013135.0%, with coefficient of variation values between 5.2 and 5.4%, respectively, for [(La<jats:sub>0.9<\/jats:sub>Sm<jats:sub>0.1<\/jats:sub>)<jats:sub>2<\/jats:sub>(DPA)<jats:sub>3<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>3<\/jats:sub>]<jats:sub>\u221e<\/jats:sub> sorbent. Detection and quantification limits ranged from 16.0 to 67.0\u00a0\u03bcg\/kg and from 50.0 to 200.0\u00a0\u03bcg\/kg, respectively, for the different pesticides studied. The results were compared with literature data. The developed and validated method was applied to real samples. The analysis detected the presence of residues of pesticides procymidone, fenbuconazole, flumetralin, clofentezine, atrazine, and bifenthrin.<\/jats:p>","DOI":"10.1002\/jssc.201700812","type":"journal-article","created":{"date-parts":[[2017,12,27]],"date-time":"2017-12-27T05:24:40Z","timestamp":1514352280000},"page":"1593-1599","source":"Crossref","is-referenced-by-count":22,"title":["Characterization and application of a lanthanide\u2010based metal\u2013organic framework in the development and validation of a matrix solid\u2010phase dispersion procedure for pesticide extraction on peppers <i>(Capsicum annuum L.)<\/i> with gas chromatography\u2013mass spectrometry"],"prefix":"10.1002","volume":"41","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1377-3611","authenticated-orcid":false,"given":"Alysson","family":"Santos Barreto","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental UFPE  Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paula","family":"de C\u00e1ssia da Silva Andrade","sequence":"additional","affiliation":[{"name":"Coordenadoria de Licenciatura em Qu\u00edmica IFS  Aracaju SE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00e9ssica","family":"Meira Farias","sequence":"additional","affiliation":[{"name":"Coordenadoria de Licenciatura em Qu\u00edmica IFS  Aracaju SE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adalberto","family":"Menezes Filho","sequence":"additional","affiliation":[{"name":"Coordenadoria de Licenciatura em Qu\u00edmica IFS  Aracaju SE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gilberto","family":"Fernandes de S\u00e1","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental UFPE  Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Severino","family":"Alves J\u00fanior","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental UFPE  Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,1,26]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2015.11.045"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodcont.2008.07.014"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2010.01.030"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2005.05.011"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-9936(98)00019-3"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1351\/PAC-REC-12-11-20"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr3002824"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00094C"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc34329k"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200256v"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2015.12.071"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00010B"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.08.036"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2014.09.046"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2013.07.005"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.05.043"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.03.020"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2014.06.062"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2013.08.047"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2006.03.061"},{"key":"e_1_2_7_23_1","first-page":"1","article-title":"Recent applications of metal\u2010organic frameworks in sample pretreatment","volume":"00","author":"Wang Y.","year":"2017","journal-title":"J. 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