{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T00:29:40Z","timestamp":1760920180712,"version":"build-2065373602"},"reference-count":42,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2018,3,12]],"date-time":"2018-03-12T00:00:00Z","timestamp":1520812800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21275112"],"award-info":[{"award-number":["21275112"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2018,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report the electrochemical fabrication of a poly(2,2\u2010bithiophene\u2010co\u20103\u2010methylthiophene)\u2010graphene composite coating and its application in the headspace solid\u2010phase microextraction and gas chromatography determination of benzenes (i.e., bromobenzene, 4\u2010bromotoluene, 2\u2010nitrotoluene, 3\u2010nitrotoluene and 1,2,4\u2010trichlorobenzene). The coating was uniform and showed cauliflower\u2010like microstructure. It had high thermal stability (up to 375\u00b0C) and could be used for at least 180 times of solid\u2010phase microextraction without a decrease in extraction performance. Furthermore, it presented high extraction capacity for the benzenes due to the hydrophobic effect and \u03c0\u2013\u03c0 interaction between the analytes and the coating. Under optimized extraction conditions, good linearity (correlation coefficients higher than 0.9946), wide linear range (0.01\u201350 \u03bcg\/L), and low limits of detection (5.25\u201312.5\u00a0ng\/L) were achieved for these analytes. The relative standard deviation was lower than 5.7% for five successive measurements with one fiber, and the relative standard deviation for fiber\u2010to\u2010fiber was 4.9\u20136.8% (<jats:italic>n<\/jats:italic>\u00a0=\u00a05). The solid\u2010phase microextraction and gas chromatography method was successfully applied for the determination of three real samples, and the recoveries for standards added were 89.6\u2013106% for nail polish, 85.8\u2013110% for hair dye, and 90\u2013106.2% for correction fluid, respectively.<\/jats:p>","DOI":"10.1002\/jssc.201701330","type":"journal-article","created":{"date-parts":[[2018,2,13]],"date-time":"2018-02-13T02:22:56Z","timestamp":1518488576000},"page":"2197-2206","source":"Crossref","is-referenced-by-count":5,"title":["Graphene\u2010doped electrochemical copolymer coating of 2,2\u2010bithiophene and 3\u2010methylthiophene for the highly effective solid\u2010phase microextraction of volatile benzene homologues"],"prefix":"10.1002","volume":"41","author":[{"given":"Xiafei","family":"Guo","sequence":"first","affiliation":[{"name":"Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education) College of Chemistry and Molecular Science Wuhan University  Wuhan P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Faqiong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education) College of Chemistry and Molecular Science Wuhan University  Wuhan P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0092-5727","authenticated-orcid":false,"given":"Baizhao","family":"Zeng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education) College of Chemistry and Molecular Science Wuhan University  Wuhan P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,3,12]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.06.049"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-017-0286-x"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.03.039"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.02.038"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.11.007"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2017.02.034"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.10.081"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2015.11.013"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.12.046"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.11.003"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.10.041"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6AY02632J"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00604-014-1320-8"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201300633"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0032-3861(89)90146-8"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2016.05.004"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4AY01552E"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2016.01.017"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b05793"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.synthmet.2014.03.031"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.44182"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijleo.2012.08.096"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1088\/0964-1726\/16\/6\/066"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2009.12.014"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00396-015-3791-5"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.25861"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tibtech.2011.01.008"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2010.08.008"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901678"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.11.025"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201601391"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm02865g"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac201864f"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(99)00205-3"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2015.08.044"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1080\/00914037.2013.845186"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep20496"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3an01937c"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH14353"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.06.049"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.03.039"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2014.08.080"}],"container-title":["Journal of Separation Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fjssc.201701330","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.201701330","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T10:54:01Z","timestamp":1760871241000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jssc.201701330"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,3,12]]},"references-count":42,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2018,5]]}},"alternative-id":["10.1002\/jssc.201701330"],"URL":"https:\/\/doi.org\/10.1002\/jssc.201701330","archive":["Portico"],"relation":{},"ISSN":["1615-9306","1615-9314"],"issn-type":[{"type":"print","value":"1615-9306"},{"type":"electronic","value":"1615-9314"}],"subject":[],"published":{"date-parts":[[2018,3,12]]}}}