{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T16:00:50Z","timestamp":1760889650198,"version":"build-2065373602"},"reference-count":31,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T00:00:00Z","timestamp":1531785600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004759","name":"Isfahan University of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004759","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2018,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this work we seek clues to select the appropriate dispersive liquid\u2013liquid microextraction mode for extracting three categories of compounds. For this purpose, three common dispersive liquid\u2013liquid microextraction modes were compared under optimized conditions. Traditional dispersive liquid\u2013liquid microextraction, in situ ionic liquid dispersive liquid\u2013liquid microextraction, and conventional ionic liquid dispersive liquid\u2013liquid microextraction using chloroform, 1\u2010butyl\u20103\u2010methylimidazolium tetrafluoroborate, and 1\u2010hexyl\u20103\u2010methylimidazolium hexafluorophosphate as the extraction solvent, respectively, were considered in this work. Phenolic, neutral aromatic, and amino compounds (each category included six members) were studied as analytes. The analytes in the extracts were determined by high\u2010performance liquid chromatography with UV detection. For the analytes with polar functionalities, the in situ ionic liquid dispersive liquid\u2013liquid microextraction mode mostly led to better results. In contrast, for neutral hydrocarbons without polar functionalities, traditional dispersive liquid\u2013liquid microextraction using chloroform produced better results. In this case, where dispersion forces were the dominant interactions in the extraction, the refractive index of solvent and analyte predicted the extraction performance better than the octanol\/water partition coefficient. It was also revealed that none of the methods were successful in extracting hydrophilic analytes (compounds with the log octanol\/water partition coefficient\u00a0&lt;2). The results of this study could be helpful in selecting a dispersive liquid\u2013liquid microextraction mode for the extraction of various groups of compounds.<\/jats:p>","DOI":"10.1002\/jssc.201800133","type":"journal-article","created":{"date-parts":[[2018,6,21]],"date-time":"2018-06-21T20:12:15Z","timestamp":1529611935000},"page":"3275-3284","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Comparison of three different dispersive liquid\u2013liquid microextraction modes performed on their most usual configurations for the extraction of phenolic, neutral aromatic, and amino compounds from waters"],"prefix":"10.1002","volume":"41","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1570-0718","authenticated-orcid":false,"given":"Mohammad","family":"Saraji","sequence":"first","affiliation":[{"name":"Department of Chemistry Isfahan University of Technology  Isfahan Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hoda","family":"Ghambari","sequence":"additional","affiliation":[{"name":"Department of Chemistry Isfahan University of Technology  Isfahan Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,7,17]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2006.03.007"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201600758"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201600405"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201700123"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-013-7467-z"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201700992"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201700270"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201700498"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201700042"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2017.04.012"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr1003248"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja028156h"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2013.06.008"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2014.12.011"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2014.08.018"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac071555g"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2014.05.007"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2018.01.094"},{"journal-title":"J. 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