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To prepare an electrochemically controlled fiber\u2010in\u2010tube solid\u2010phase microextraction column, first eight stainless\u2010steel wires were placed into the stainless\u2010steel column. Then, a nanostructured Cu\u2010Cr\u2010Al ternary layered double hydroxide\/polythiophene coating was prepared on the inner surface of the stainless\u2010steel tube and on the surfaces of the stainless\u2010steel wires by a facile in situ electrodeposition method. The nanostructured coating exhibited enhanced long lifetime, good mechanical stability, high porosity, and large specific surface area compared with polythiophene and Cu\u2010Cr\u2010Al layered double hydroxide coatings. Under the optimal conditions, the limits of detection were in the range of 0.07\u20130.8 \u03bcg\/L. This method showed good linearity for perphenazine and chlorpromazine in the ranges of 0.3\u2013300 and 0.2\u2013300 \u03bcg\/L, respectively, with coefficients of determination more than 0.9982. The inter\u2010 and intra\u2010assay precisions (RSD%, <jats:italic>n<\/jats:italic>\u00a0=\u00a03) were in the ranges of 3.0\u20135.1 and 2.5\u20134.5% at three concentration levels of 5, 25 and 50 \u03bcg\/L, respectively. Finally, the method was applied for the analysis of the drugs in human urine and plasma samples.<\/jats:p>","DOI":"10.1002\/jssc.201800417","type":"journal-article","created":{"date-parts":[[2018,7,24]],"date-time":"2018-07-24T03:49:42Z","timestamp":1532404182000},"page":"3598-3606","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Electrochemically controlled fiber\u2010in\u2010tube solid\u2010phase microextraction method for the determination of trace amounts of antipsychotic drugs in biological samples"],"prefix":"10.1002","volume":"41","author":[{"given":"Maryam","family":"Shamsayei","sequence":"first","affiliation":[{"name":"Department of Chemistry Tarbiat Modares University  Tehran Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2484-9477","authenticated-orcid":false,"given":"Yadollah","family":"Yamini","sequence":"additional","affiliation":[{"name":"Department of Chemistry Tarbiat Modares University  Tehran Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hamid","family":"Asiabi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Tarbiat Modares University  Tehran Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,8,12]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00218a019"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100203t"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-008-2375-3"},{"key":"e_1_2_8_5_1","first-page":"103","article-title":"New trends in solid\u2010phase microextraction","volume":"27","author":"Eisert R.","year":"1997","journal-title":"Anal. 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