{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T13:22:15Z","timestamp":1788355335889,"version":"build-2803163510"},"reference-count":25,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2020,11,19]],"date-time":"2020-11-19T00:00:00Z","timestamp":1605744000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2021,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Four novel regioselectively carbamoylated cellulose derivatives with two types of substituents, one being a 3\u2010chloro\u20104\u2010methylphenylcarbamate group and the other being a phenylcarbamate, a 3,5\u2010dichlorophenylcarbamate or a 4\u2010methylphenylcarbamate group, at the 2\u2010, 3\u2010positions and 6\u2010position were synthesized and utilized as chiral stationary phases in high\u2010performance liquid chromatography. The obtained derivatives exhibited characteristic chiral recognition abilities which were significantly affected by the nature and arrangement of the groups at the 2\u2010, 3\u2010positions and 6\u2010position. Compared with cellulose tris(3\u2010chloro\u20104\u2010methylphenylcarbamate) and Chiralcel OD columns, several racemates were better resolved on these new phases. With all six racemates resolved on cellulose 2,3\u2010bis(4\u2010methylphenylcarbamate)\u20106\u2010(3\u2010chloro\u20104\u2010methylphenylcarbamate), it appears to be a potential useful chiral stationary phase in the future. Also, the influence of mobile phase on chiral recognition was investigated. Better resolutions were generally obtained with decreased amount of 2\u2010propanol with a mixture of hexane\/2\u2010propanol as the mobile phase. Moreover, when ethanol was used instead of 2\u2010propanol as the mobile phase modifier, poorer enantioseparations were often achieved.<\/jats:p>","DOI":"10.1002\/jssc.202000912","type":"journal-article","created":{"date-parts":[[2020,11,2]],"date-time":"2020-11-02T03:33:21Z","timestamp":1604288001000},"page":"489-496","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Enantiomer separation on novel cellulose derivatives bearing regioselective phenylcarbamate groups"],"prefix":"10.1002","volume":"44","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0228-8912","authenticated-orcid":false,"given":"Shouwan","family":"Tang","sequence":"first","affiliation":[{"name":"Department of Chemistry School of Pharmaceutical and Materials Engineering Taizhou University  Tauzhou P. R. 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