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Conductive vials can simultaneously perform as electrodes therefore, there is no need to include an electrode in sample solutions. Phenobarbital and phenytoin were used as model compounds to assess the setup performance. Under optimal conditions, these analytes were extracted from the sample solution at pH\u00a0=\u00a09 to the acceptor solution at pH\u00a0=\u00a013 with a voltage of 40 V for 20\u00a0min, while 1\u2010octanol was employed as the supported\u2010liquid\u2010membrane. The influence of conductive vials geometry on the recovery was examined and the effects of different shapes were studied by performing numerical simulation to establish electric potential distribution. Of the vials tested with circular, triangular, and floral\u2010like cross\u2010sections the latter exhibited the best voltage distribution. The circular vial had the highest recovery attributed to its better hydrodynamic shape, which allows rapid fluid sample transport and therefore enhanced system recovery. The extraction recovery and relative standard deviation of the circular vial with three fibers were 33.0 and 7.6 for phenobarbital and 42.2 and 10.4 for phenytoin.<\/jats:p>","DOI":"10.1002\/jssc.202200028","type":"journal-article","created":{"date-parts":[[2022,6,28]],"date-time":"2022-06-28T02:43:54Z","timestamp":1656384234000},"page":"3187-3196","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["A novel three\u2010dimensional printed device with conductive elements for electromembrane extraction combined with high\u2010performance liquid chromatography and ultraviolet detector"],"prefix":"10.1002","volume":"45","author":[{"given":"Roshanak","family":"Dolatabadi","sequence":"first","affiliation":[{"name":"Department of Drug and Food Control, Faculty of Pharmacy Tehran University of Medical Sciences  Tehran Iran"},{"name":"Food and Drug Administration Iran Ministry of Health and Medical Education  Tehran 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