{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T14:32:34Z","timestamp":1789050754647,"version":"build-2803163510"},"reference-count":36,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2023,8,15]],"date-time":"2023-08-15T00:00:00Z","timestamp":1692057600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2023,10]]},"abstract":"<jats:p>This study used reversed\u2010phase liquid chromatography\u2013tandem mass spectrometry and supercritical fluid chromatography\u2013tandem mass spectrometry for determination of the stereoisomers of chlorfenvinphos and dimethylvinphos in tobacco. Tobacco samples were extracted and purified with a modified quick, easy, cheap, effective, rugged, and safe technique using spherical carbon. The performance of both methodologies was comprehensively compared in terms of methods validation parameters (separation efficiency, linearity, selectivity, recovery, repeatability, sensitivity, matrix effect, etc.). Under optimized conditions, the calibration curves of the stereoisomers of chlorfenvinphos and dimethylvinphos in the range of 10\u2013500\u00a0ng\/mL showed excellent linearity with <jats:italic>R<\/jats:italic><jats:sup>2<\/jats:sup> \u2265 \u20090.997 in both methods. The adequate recoveries of analytes from three different spiked tobaccos were obtained using reversed\u2010phase liquid chromatography\u2013tandem mass spectrometry (86.1\u201395.7%) as well as supercritical fluid chromatography\u2013tandem mass spectrometry (86.5\u201394.0%). The relative standard deviations for spiked samples were all below 7.0%. Compared with supercritical fluid chromatography\u2013tandem mass spectrometry, lower matrix effects and LODs can be obtained in reversed\u2010phase liquid chromatography\u2013tandem mass spectrometry.<\/jats:p>","DOI":"10.1002\/jssc.202300449","type":"journal-article","created":{"date-parts":[[2023,8,19]],"date-time":"2023-08-19T00:33:59Z","timestamp":1692405239000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Comparison of supercritical fluid chromatography\u2013tandem mass spectrometry and liquid chromatography\u2013tandem mass spectrometry for the stereoselective analysis of chlorfenvinphos and dimethylvinphos in tobacco"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8839-1015","authenticated-orcid":false,"given":"Fei","family":"Yang","sequence":"first","affiliation":[{"name":"China National Tobacco Quality Supervision and Test Center  Zhengzhou P. R. 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