{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T19:30:41Z","timestamp":1793647841183,"version":"4.5.1"},"reference-count":21,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2023,12,8]],"date-time":"2023-12-08T00:00:00Z","timestamp":1701993600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2024,1]]},"abstract":"<jats:p>A supercritical fluid chromatography\u2010tandem mass spectrometry (SFC\u2010MS\/MS) technique was developed for the rapid and simultaneous detection of nine pesticides (carbendazim, isoprocarb, paclobutrazol, isoprothiolane, flusilazole, quinalphos, piperonylbutoxide, propargite, and bioresmethrin) in rice, wheat, and maize. The cereal samples were extracted with a solution of 0.5% acetic acid in acetonitrile and purified using quick, easy, cheap, effective, rugged, and safe method. The samples were characterized using multi\u2010reaction monitoring and quantified with the external standard method. Excellent linearities (<jats:italic>R<\/jats:italic><jats:sup>2<\/jats:sup>\u00a0&gt;\u00a00.9991) and limits of quantification (0.4\u201340.0\u00a0\u03bcg\/kg) were established for all nine pesticides. Satisfactory pesticide recovery rates (62.2%\u2013107.4%) were obtained at three standard concentrations (50, 100, and 200\u00a0\u03bcg\/kg), with relative standard deviations in the range of 2.1%\u201314.3%. The results confirmed that the proposed method was suitable for the routine detection of these pesticides in grain samples. Compared with high\u2010performance liquid chromatography\u2010MS\/MS, the overall test run time and the amount of solvent required were reduced by 66% and 90%, respectively, when SFC\u2010MS\/MS was applied. Therefore, the use of SFC\u2010MS\/MS permits a shorter run time and affords greater analytical efficiency, such that it is both economical and environmentally sustainable.<\/jats:p>","DOI":"10.1002\/jssc.202300623","type":"journal-article","created":{"date-parts":[[2023,12,8]],"date-time":"2023-12-08T23:10:35Z","timestamp":1702077035000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Evaluation of supercritical fluid chromatography coupled to tandem mass spectrometry for the analysis of pesticide residues in grain"],"prefix":"10.1002","volume":"47","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-1813-2702","authenticated-orcid":false,"given":"Tingting","family":"Xie","sequence":"first","affiliation":[{"name":"Institute of Grain and Oil Quality Supervision and Test of Fujian Province  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianli","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute of Grain and Oil Quality Supervision and Test of Fujian Province  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Jinshan Fujian Agriculture and Forestry University Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingling","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Grain and Oil Quality Supervision and Test of Fujian Province  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,8]]},"reference":[{"key":"e_1_2_7_2_1","article-title":"Catechol functionalized hat\u2010shape carriers for prolonging pesticide retention and flush resistance on foliage","author":"Zhao K","year":"2020","journal-title":"Chem Eng J"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.7b02004"},{"issue":"1","key":"e_1_2_7_4_1","first-page":"852","article-title":"Recent advances in rapid detection of pesticide residues","volume":"21","author":"Wang DW","year":"2019","journal-title":"Chin J Pestic Sci"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultsonch.2023.106356"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202100304"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2012.08.100"},{"issue":"14","key":"e_1_2_7_8_1","first-page":"1676","article-title":"Determination of trichlorfon pesticide residues in vegetables and its degradation product (dichlorvos) by gas chromatography method","volume":"28","author":"Ma Y","year":"2018","journal-title":"Chin J Heal Lab Technol"},{"issue":"14","key":"e_1_2_7_9_1","first-page":"20","article-title":"Rapid determination of 7 pesticide residues in vegetables and fruits by MSPD\u2010HPLC","volume":"36","author":"Zhang C","year":"2016","journal-title":"Guide Chin Med"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201801163"},{"issue":"26","key":"e_1_2_7_11_1","first-page":"16465","article-title":"Advances and trends in testing technology for residue pesticide of agricultural products","volume":"39","author":"Zeng X","year":"2011","journal-title":"J Anhui Agr"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2016.01.002"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2019.04.063"},{"key":"e_1_2_7_14_1","first-page":"1059","article-title":"Supercritical fluid chromatography coupled to tandem mass spectrometry for the analysis of pesticide residues in dried spices. 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