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Extraction was performed using a plastic syringe, eliminating the use of any electrical power source. Di\u2010(2\u2010ethylhexyl) phosphoric acid (DEHPA) served as the extractant. The process initially involved dissolving DEHPA in an alkaline solution to obtain a homogeneous solution. Subsequently, the sodium salt of DEHPA was precipitated by salting\u2010out, and the resulting heterogeneous mixture was filtered using a syringe filter. The precipitate containing the analytes was then dissolved in methanol for analysis by high\u2010performance liquid chromatography. Under optimal conditions, extraction recovery for chloroanilines ranged from 26% to 71%. Method linearity was evaluated within a concentration range of 1.0\u2013100\u00a0\u00b5g\/L, resulting in coefficients of determination exceeding 0.9987 for all analytes. Method detection limits ranged from 0.28 to 0.41\u00a0\u00b5g\/L. Intra and inter\u2010day precision values were below 9.5% and 10.8%, respectively. The developed method was applied to determine chloroanilines in real waters, yielding acceptable recoveries ranging from 80% to 109% for spiked tap, rain, and stream waters. Additionally, the method was successfully employed for on\u2010site extraction of target contaminants, demonstrating no statistically significant differences compared to laboratory results.<\/jats:p>","DOI":"10.1002\/jssc.202400124","type":"journal-article","created":{"date-parts":[[2024,5,21]],"date-time":"2024-05-21T21:13:57Z","timestamp":1716326037000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["In\u2010syringe homogeneous liquid\u2010phase microextraction followed by filtration\u2010based phase separation for on\u2010site extraction of chloroanilines from water samples"],"prefix":"10.1002","volume":"47","author":[{"given":"Elif","family":"Y\u0131ld\u0131z","sequence":"first","affiliation":[{"name":"Zonguldak B\u00fclent Ecevit University Faculty of Sciences, Department of Chemistry  Zonguldak 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