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The method employs hollow fiber\u2010microporous membrane liquid\u2010liquid microextraction combined with a 96\u2010well plate system, utilizing fatty\u2010acid\u2010based DES in the pores of the membranes. This methodology substantially reduces the use of organic solvents, and its efficiency is comparable to or better than conventional methods. Fatty acids with chain lengths ranging from 6 to 12 carbons were investigated for the determination of dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), and benzyl butyl phthalate (BBP). The optimized approach used a NADES of decanoic and nonanoic acids (2:3 molar ratio), with 60\u00a0min of extraction and 30\u00a0min of desorption in acetonitrile:methanol (1:1 ratio). Limits of detection were reported as 8.2\u00a0\u00b5g\/L for DMP, 7.6\u00a0\u00b5g\/L for DEP and DBP, and 3.0\u00a0\u00b5g\/L for BBP. Intraday precision ranged from 2.2% to 18.6% and inter\u2010day precision from 8.8% to 18.8%. Relative recovery across 3 levels ranged from 83.1% to 113.5%. The methodology was evaluated by two tools with green metrics to indicate sustainability. Analytes are extracted, quantified, and confirmed as phthalates in two brands of carbonated soft drinks.<\/jats:p>","DOI":"10.1002\/jssc.70060","type":"journal-article","created":{"date-parts":[[2024,12,24]],"date-time":"2024-12-24T02:29:24Z","timestamp":1735007364000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Quantification of Phthalate Esters in Carbonated Soft Drinks by Hollow Fiber\u2010Microporous Membrane Liquid\u2010Liquid Extraction and 96\u2010Well Plate System Using Natural Deep Eutectic Solvents Based on Fatty Acids"],"prefix":"10.1002","volume":"47","author":[{"given":"Diogo C.","family":"Morelli","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Universidade Federal de Santa Catarina  Florianopolis Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lucas","family":"Mor\u00e9s","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica 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