{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T03:02:58Z","timestamp":1789095778238,"version":"build-2803163510"},"reference-count":40,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,1,24]],"date-time":"2025-01-24T00:00:00Z","timestamp":1737676800000},"content-version":"vor","delay-in-days":23,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2025,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title><jats:p>Polycyclic aromatic hydrocarbons (PAHs) are carcinogenic compounds resulting from incomplete burning of organic materials. This work describes the successful layer\u2010by\u2010layer fabrication of a novel zinc oxide nanocomposite made of zinc oxide nanoparticles, aniline, sodium dodecyl sulfate, and modified multi\u2010walled carbon nanotubes on a stainless steel wire by electrodeposition. The coating and extraction conditions were screened, optimized, and validated using factorial design and central composite design, respectively. The prepared nanocomposites were characterized by the Fourier\u2010transform infrared spectroscopy, field\u2010emission scanning electron microscopy, X\u2010ray diffraction analysis, and Brunauer\u2010Emmett\u2010Teller techniques. It featured a porous structure, excellent heat stability, and a high extraction capacity. It also adhered well to the steel surface. Extracting PAHs was optimized through experimental design. The optimal conditions obtained for extraction were 60\u00a0min, 30%, and 30\u00b0C for extraction time, amount of salt, and extraction temperature, respectively. The validated method generally showed a linear range between 0.01 to 1.50 \u00b5g\/mL with a linearity of (R<jats:sup>2<\/jats:sup>) of 0.9902\u20130.9992, limits of detection less than 0.003 \u00b5g\/mL, limit of quantification lower than 0.010 \u00b5g\/mL, and relative standard deviation percent less than 45. Recovery values of the analytes in food samples varied between 53.4% and 110.1%. The proposed method was employed in the extraction and determination of some PAHs in some food samples while naphthalene, anthracene, phenanthrene, benzo[a]pyrene, and benz[a]anthracene were detected in certain food samples. Overall, our research suggests a novel nanocomposite as a potential fiber coating that enables high\u2010capacity PAH extraction.<\/jats:p>","DOI":"10.1002\/jssc.70080","type":"journal-article","created":{"date-parts":[[2025,1,25]],"date-time":"2025-01-25T01:20:42Z","timestamp":1737768042000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electrochemical Synthesis of Polyaniline@Nano Zinc Oxide\/Modified Multiwalled Carbon Nanotubes Nanocomposite Coating for Solid Phase Microextraction of Some Polycyclic Aromatic Hydrocarbons in Coffee and Grilled Meat"],"prefix":"10.1002","volume":"48","author":[{"given":"Rezvan Askari","family":"Baduee","sequence":"first","affiliation":[{"name":"Department of Chemistry Kerman Branch Islamic Azad University  Kerman Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8485-3291","authenticated-orcid":false,"given":"Maryam","family":"Kazemipour","sequence":"additional","affiliation":[{"name":"Department of Chemistry Kerman Branch Islamic Azad University  Kerman Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4637-553X","authenticated-orcid":false,"given":"Mehdi","family":"Ansari","sequence":"additional","affiliation":[{"name":"Department of Drug and Food Control Faculty of Pharmacy Kerman University of Medical Sciences  Kerman Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohammad","family":"Mehdipour","sequence":"additional","affiliation":[{"name":"Pharmaceutical Science and Cosmetic Products Research Center Kerman University of Medical Sciences  Kerman Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Neda","family":"Mohamadi","sequence":"additional","affiliation":[{"name":"Herbal and Traditional Medicines Research Center Kerman University of Medical Sciences  Kerman Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10311-017-0697-0"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tifs.2018.11.015"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2017.10.336"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/elps.201900111"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2009.08.001"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1155\/2010\/398381"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2021.107147"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(92)87020-L"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA04103E"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpba.2018.06.052"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202400082"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2009.12.035"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2023.138384"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2018.05.050"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2019.03.025"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2004.11.028"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10098-021-02104-0"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.arabjc.2017.12.020"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2023.109011"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2012.03.008"},{"key":"e_1_2_8_22_1","first-page":"1481","article-title":"Photocatalytic Degradation of Congo Red Dye via Multi\u2010walled Carbon Nanotubes Modified CuO and ZnO Nanoparticles Under Visible Light Irradiation","volume":"64","author":"Alkahlawy A.","year":"2021","journal-title":"Egyptian Journal of Chemistry"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2021.106364"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodcont.2021.108104"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2022.128288"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2024.125750"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2021.122764"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202400296"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2018.04.040"},{"key":"e_1_2_8_30_1","article-title":"Determination of Polycyclic Aromatic Hydrocarbons in Water Samples Using Solid\u2010Phase Extraction Procedure and High\u2010Performance Liquid Chromatography with Fluorescence Detection","author":"Ghanmi S.","year":"2024","journal-title":"Separation Science Plus"},{"key":"e_1_2_8_31_1","unstructured":"H.Isah Synthesis and Characterizations of ZnO and ZnO\/CNT Nanocomposites for Application in Solar Cell 2021 Master of Technology."},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1080\/17518253.2021.1970243"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.powtec.2010.05.014"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2005.10.001"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1080\/01932691.2020.1740728"},{"key":"e_1_2_8_36_1","first-page":"1","article-title":"Solid Phase Microextraction of Polycyclic Aromatic Hydrocarbons by Using an Etched Stainless\u2010steel fiber Coated With a Covalent Organic Framework","volume":"186","author":"Yang X.","year":"2019","journal-title":"Mikrochimica Acta"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2019.06.063"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2020.461428"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2020.461354"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.201800862"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/jssc.202000047"}],"container-title":["Journal of Separation Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jssc.70080","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T14:28:59Z","timestamp":1760884139000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/jssc.70080"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1]]},"references-count":40,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,1]]}},"alternative-id":["10.1002\/jssc.70080"],"URL":"https:\/\/doi.org\/10.1002\/jssc.70080","archive":["Portico"],"relation":{},"ISSN":["1615-9306","1615-9314"],"issn-type":[{"value":"1615-9306","type":"print"},{"value":"1615-9314","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1]]},"assertion":[{"value":"2024-07-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-07","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70080"}}