{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T15:59:53Z","timestamp":1787500793676,"version":"build-2736575974"},"reference-count":60,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2025,5,10]],"date-time":"2025-05-10T00:00:00Z","timestamp":1746835200000},"content-version":"vor","delay-in-days":9,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,5,1]],"date-time":"2025-05-01T00:00:00Z","timestamp":1746057600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100005357","name":"Agent\u00fara na Podporu V\u00fdskumu a V\u00fdvoja","doi-asserted-by":"publisher","award":["1\/0332\/24"],"award-info":[{"award-number":["1\/0332\/24"]}],"id":[{"id":"10.13039\/501100005357","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    This study demonstrates the development of HPLC\u2010DAD method for determination of D\u2010panthenol incorporating the molecularly imprinted solid\u2010phase extraction for sample preparation. Two types of adsorbents, molecularly imprinted polymers synthesized by bulk polymerization (MIPs) and precipitation polymerization on the surface of magnetic particles (Fe\u2083O\u2084@MIP), were compared in terms of adsorption properties and application potential. D\u2010panthenol, a bioactive compound of pharmaceutical and cosmetic products, was used as the template for imprinting. The optimal polymerization mixture included 4\u2010vinylpyridine as the functional monomer and methanol as the porogenic solvent. The adsorption kinetics of the pseudo\u2010second\u2010order indicated chemisorption of the template onto the active sites of the adsorbent. The Freundlich isotherm adsorption model, which fitted experimental data, suggested the presence of heterogeneous sorption sites on the adsorbents. MIPs and Fe\u2083O\u2084@MIPs were employed as adsorbents for the solid\u2010phase extraction of D\u2010panthenol from various cosmetic samples (such as body milk and other personal care products) achieving good selectivity for the targeted substance. Recoveries of MIP\u2010 and Fe\u2083O\u2084@MIP\u2010based extractions were 82.3% (RSD &lt; 2.9%) and 85.8% (RSD &lt; 3.6%), respectively. The proposed HPLC\u2010DAD method exhibited satisfactory linearity over the concentration range of 5.6\u2013100 \u00b5g\u00a0mL\u207b\u00b9 (\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    = 0.9989) and a limit of detection of 1.7 \u00b5g\u00a0mL\u207b\u00b9.\n                  <\/jats:p>","DOI":"10.1002\/jssc.70161","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T05:18:21Z","timestamp":1748323101000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Molecularly Imprinted Adsorbent and Its Magnetic Version for Solid Phase Extraction of D\u2010Panthenol: Comparison of Synthesis Approaches, Properties, and Applicability for Different Real Samples Extraction"],"prefix":"10.1002","volume":"48","author":[{"given":"Andrea","family":"\u0160pa\u010dkov\u00e1","sequence":"first","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Analytical Chemistry Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandra","family":"Sol\u010dianska\u2010Schwarz","sequence":"additional","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Analytical Chemistry Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michaela","family":"K\u00f6v\u00e9rov\u00e1","sequence":"additional","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Analytical Chemistry Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Izabela","family":"Luka\u010dovi\u010d Vajov\u00e1","sequence":"additional","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Natural and Synthetic Polymers Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Radko","family":"Ti\u0148o","sequence":"additional","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Natural and Synthetic Polymers Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katar\u00edna","family":"Hrobo\u0148ov\u00e1","sequence":"additional","affiliation":[{"name":"Faculty of Chemical and Food Technology Institute of Analytical Chemistry Slovak University of Technology in Bratislava  Bratislava Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,10]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3LP00203A"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules27217355"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25214869"},{"key":"e_1_2_8_5_1","unstructured":"Are All Personal Care Products Regulated as Cosmetics? 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