{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T10:29:12Z","timestamp":1786616952489,"version":"build-2736575974"},"reference-count":43,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"vor","delay-in-days":9,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Separation Science"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    A selective phase for tetracycline antibiotics (TAs) uptake was designed by incorporating [BMIM][PF\n                    <jats:sub>6<\/jats:sub>\n                    ]\u2010functionalized ZIF\u201067\u2010derived carbonaceous material into the\u00a0diffusive gradients in a thin\u2010films (DGT) device. This material, integrated in the binding gel of DGT (ta\u2010DGT), exhibited specifically strong affinity toward tetracycline (TC), oxytetracycline (OTC), and chlortetracycline (CTC), with adsorption capacities of 12.22, 11.81, and 13.78\u00a0\u00b5g\/disc, respectively. The ta\u2010DGT showed preferential uptake of TAs over coexisting antibiotics and organic contaminants, with adsorption ratios above 80% and stable performance over pH 4\u20139 and ionic strength of 0.001\u20130.1\u00a0M. Mechanistic analysis indicated that \u03c0\u2013\u03c0 electron donor\u2013acceptor interactions and cation\u2013\u03c0 bonding facilitated the specific targeting of TAs onto ta\u2010DGT. During 7 days of field deployment in a domestic wastewater treatment plant in Beijing, ta\u2010DGT showed 5\u201340 times higher detectable concentrations than conventional HLB\/XAD DGT devices. These results validated its sensitivity, reliability, and feasibility for the selective separation and quantification of TAs in complex aqueous matrices.\n                  <\/jats:p>","DOI":"10.1002\/jssc.70470","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T12:43:12Z","timestamp":1783687392000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Selective Separation and Quantification of Tetracycline Antibiotics Using Ionic Liquid\u2010Functionalized MOF\u2010Derived Diffusive Gradients in Thin Films"],"prefix":"10.1002","volume":"49","author":[{"given":"Hanbing","family":"Li","sequence":"first","affiliation":[{"name":"Department of Environmental Science Key Laboratory of Beijing on Regional Air Pollution Control Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Environmental Science Key Laboratory of Beijing on Regional Air Pollution Control Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuyang","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Environmental Science Key Laboratory of Beijing on Regional Air Pollution Control Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaming","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing Drainage Group Co. 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